DOI

We consider distortions of the shapes of absorption bands of strongly scattering samples in the spectra of molecules adsorbed on the surface of dispersed solids. We show that the influence of the scattering on IR spectra of dispersed samples is not reduced merely to a weakening of the intensity of the transmitted light, but, rather, the scattering affects the contour of a spectral band due to changes in the refractive index of the substance in the range of the absorption band. Using carbon dioxide adsorbed on a NaX zeolite as an example, we demonstrate two methods for taking into account the contribution of the scattering to the spectra of surface compounds: the registration of the “diffuse-transmission” spectrum and placing a sample into an immersion liquid, for which liquid oxygen is used. The obtained spectra indicate that, if the zeolite is saturated with the adsorbate, the band of the antisymmetric stretching vibration of CO2 molecules broadens and reveals a complex structure as a result of the resonant dipole–dipole interaction between adsorbed molecules.

Язык оригиналаанглийский
Страницы (с-по)655-659
Число страниц5
ЖурналOptics and Spectroscopy (English translation of Optika i Spektroskopiya)
Том124
Номер выпуска5
DOI
СостояниеОпубликовано - 1 мая 2018

    Предметные области Scopus

  • Электроника, оптика и магнитные материалы
  • Атомная и молекулярная физика и оптика

ID: 41679907