DOI

A magnetic field modifies optical properties and provides valley splitting in a molybdenum disulfide (MoS2) monolayer. Here we demonstrate a scalable approach to the epitaxial synthesis of MoS2 monolayer on a magnetic graphene/Co system. Using spin- and angle-resolved photoemission spectroscopy we observe a magnetic proximity effect that causes a 20 meV spin-splitting at the point and canting of spins at the K̄ point in the valence band toward the in-plane direction of cobalt magnetization. Our density functional theory calculations reveal that the in-plane spin component at K̄ is localized on Co atoms in the valence band, while in the conduction band it is localized on the MoS2 layer. The calculations also predict a 16 meV spin-splitting at the point and 8 meV K̄ -K′¯ valley asymmetry for an out-of-plane magnetization. These findings suggest control over optical transitions in MoS2 via Co magnetization. Our estimations show that the magnetic proximity effect is equivalent to the action of the magnetic field as large as 100 T.

Язык оригиналаанглийский
Страницы (с-по)7448-7456
ЖурналACS Nano
Том16
Номер выпуска5
DOI
СостояниеОпубликовано - 20 апр 2022

    Предметные области Scopus

  • Технология (все)
  • Физика и астрономия (все)
  • Материаловедение (все)

ID: 97909544