Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Direct determination of uranium and thorium in minerals by time-of-flight mass spectrometry with pulsed glow discharge. / Ganeev, A.; Bogdanova, O.; Ivanov, I.; Burakov, B.; Agafonova, N.; Korotetski, B.; Gubal, A.; Solovyev, N.; Iakovleva, E.; Sillanpää, M.
в: RSC Advances, Том 5, № 99, 2015, стр. 80901-80910.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Direct determination of uranium and thorium in minerals by time-of-flight mass spectrometry with pulsed glow discharge
AU - Ganeev, A.
AU - Bogdanova, O.
AU - Ivanov, I.
AU - Burakov, B.
AU - Agafonova, N.
AU - Korotetski, B.
AU - Gubal, A.
AU - Solovyev, N.
AU - Iakovleva, E.
AU - Sillanpää, M.
PY - 2015
Y1 - 2015
N2 - A direct method of uranium and thorium determination in non-conducting geological samples using time-of-flight mass spectrometry with pulsed glow discharge was proposed. The following rock specimens were analysed: metamict zircon, metamict rinkite, metamict samarskite (Y–Fe-niobate), pyrochlore and jacinth. For sample sputtering a combined hollow cathode cell of high purity aluminium or tantalum hollow cathodes was used. Powdered or monolith samples were pressed into the surface of the powdered metal prior to analysis. Model samples (artificial mixtures of oxides) were proposed for calibration; additionally, relative sensitivity factors, internal standardisation and standard additions were employed. For validation, IAEA artificially prepared uranium ore reference material was analysed. For additional validation, the obtained results for real mineral samples were compared to the results of inductively coupled plasma optical emission spectrometry after sample dissolution and semi-quantitative data of energy dis
AB - A direct method of uranium and thorium determination in non-conducting geological samples using time-of-flight mass spectrometry with pulsed glow discharge was proposed. The following rock specimens were analysed: metamict zircon, metamict rinkite, metamict samarskite (Y–Fe-niobate), pyrochlore and jacinth. For sample sputtering a combined hollow cathode cell of high purity aluminium or tantalum hollow cathodes was used. Powdered or monolith samples were pressed into the surface of the powdered metal prior to analysis. Model samples (artificial mixtures of oxides) were proposed for calibration; additionally, relative sensitivity factors, internal standardisation and standard additions were employed. For validation, IAEA artificially prepared uranium ore reference material was analysed. For additional validation, the obtained results for real mineral samples were compared to the results of inductively coupled plasma optical emission spectrometry after sample dissolution and semi-quantitative data of energy dis
KW - uranium
KW - thorium
KW - minerals
KW - glow discharge mass spectrometry
KW - inductively coupled plasma optical emission spectrometry
KW - secondary cathode
U2 - 10.1039/c5ra13312b
DO - 10.1039/c5ra13312b
M3 - Article
VL - 5
SP - 80901
EP - 80910
JO - RSC Advances
JF - RSC Advances
SN - 2046-2069
IS - 99
ER -
ID: 3945450