DOI

  • O. A. Dommes
  • O. V. Okatova
  • A. A. Kostina
  • I. I. Gavrilova
  • E. F. Panarin
  • G. M. Pavlov

Fractions of the copolymer of N-methyl-N-vinylacetamide and N-methyl-N-vinylamine hydrochloride containing 15.7 ± 0.5% of charged units are obtained by radical polymerization, fractionation, and hydrolysis. Viscous flow, velocity sedimentation, and translational diffusion of their dilute solutions are studied in 0.2 M NaCl. Viscosimetric studies are also carried out in a wide range of ionic forces: from the minimum (~10–6 mol/L) to the maximum (6 mol/L). The hydrodynamic volumes and equilibrium rigidity of the copolymer under study are compared with the data obtained earlier for an uncharged homopolymer and a copolymer with a higher linear charge density (~44% of charged units) in solutions with different ionic strength. The correspondence of the values obtained to the theories of Odijk, Skolnik, and Fixman (OSF) as well as Dobrynin is discussed.

Язык оригиналаанглийский
Страницы (с-по)125-132
Число страниц8
ЖурналPolymer Science - Series C
Том59
Номер выпуска1
DOI
СостояниеОпубликовано - 1 сен 2017

    Предметные области Scopus

  • Химия (все)
  • Пластик и полимеры
  • Химия материалов

ID: 9342525