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Dilational viscoelasticity of PEO-PPO-PEO triblock copolymer films at the air-water interface in the range of high surface pressures. / Noskov, B. A.; Lin, S. Y.; Loglio, G.; Rubio, R. G.; Miller, R.

в: Langmuir, Том 22, № 6, 14.03.2006, стр. 2647-2652.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Author

Noskov, B. A. ; Lin, S. Y. ; Loglio, G. ; Rubio, R. G. ; Miller, R. / Dilational viscoelasticity of PEO-PPO-PEO triblock copolymer films at the air-water interface in the range of high surface pressures. в: Langmuir. 2006 ; Том 22, № 6. стр. 2647-2652.

BibTeX

@article{ffd5d529aae14e99a033ec5a703e5872,
title = "Dilational viscoelasticity of PEO-PPO-PEO triblock copolymer films at the air-water interface in the range of high surface pressures",
abstract = "The dynamic dilational elasticity of adsorbed and spread films of PEO-PPO-PEO triblock copolymers at the air-water interface was measured as a function of surface pressure, surface age, and frequency. At low surface pressures (< 10 mN/m), the surface viscoelasticity is identical to that of PEO homopolymer films. The results at higher surface pressures can be explained by the desorption of PPO segments from the interface and then mixing with PEO segments in water. Unlike some recent results, the spread and adsorbed films are not identical. Spread films exhibit a maximum real part of the dynamic surface elasticity of about 20 mN/m and probably begin to dissolve in water at surface pressures above 19 mN/m. However, the surface elasticity of the adsorbed films decreases beyond the maximum, indicating the formation of a loose surface structure.",
author = "Noskov, {B. A.} and Lin, {S. Y.} and G. Loglio and Rubio, {R. G.} and R. Miller",
year = "2006",
month = mar,
day = "14",
doi = "10.1021/la052662d",
language = "English",
volume = "22",
pages = "2647--2652",
journal = "Langmuir",
issn = "0743-7463",
publisher = "American Chemical Society",
number = "6",

}

RIS

TY - JOUR

T1 - Dilational viscoelasticity of PEO-PPO-PEO triblock copolymer films at the air-water interface in the range of high surface pressures

AU - Noskov, B. A.

AU - Lin, S. Y.

AU - Loglio, G.

AU - Rubio, R. G.

AU - Miller, R.

PY - 2006/3/14

Y1 - 2006/3/14

N2 - The dynamic dilational elasticity of adsorbed and spread films of PEO-PPO-PEO triblock copolymers at the air-water interface was measured as a function of surface pressure, surface age, and frequency. At low surface pressures (< 10 mN/m), the surface viscoelasticity is identical to that of PEO homopolymer films. The results at higher surface pressures can be explained by the desorption of PPO segments from the interface and then mixing with PEO segments in water. Unlike some recent results, the spread and adsorbed films are not identical. Spread films exhibit a maximum real part of the dynamic surface elasticity of about 20 mN/m and probably begin to dissolve in water at surface pressures above 19 mN/m. However, the surface elasticity of the adsorbed films decreases beyond the maximum, indicating the formation of a loose surface structure.

AB - The dynamic dilational elasticity of adsorbed and spread films of PEO-PPO-PEO triblock copolymers at the air-water interface was measured as a function of surface pressure, surface age, and frequency. At low surface pressures (< 10 mN/m), the surface viscoelasticity is identical to that of PEO homopolymer films. The results at higher surface pressures can be explained by the desorption of PPO segments from the interface and then mixing with PEO segments in water. Unlike some recent results, the spread and adsorbed films are not identical. Spread films exhibit a maximum real part of the dynamic surface elasticity of about 20 mN/m and probably begin to dissolve in water at surface pressures above 19 mN/m. However, the surface elasticity of the adsorbed films decreases beyond the maximum, indicating the formation of a loose surface structure.

UR - http://www.scopus.com/inward/record.url?scp=33645498115&partnerID=8YFLogxK

U2 - 10.1021/la052662d

DO - 10.1021/la052662d

M3 - Article

AN - SCOPUS:33645498115

VL - 22

SP - 2647

EP - 2652

JO - Langmuir

JF - Langmuir

SN - 0743-7463

IS - 6

ER -

ID: 13747057