Результаты исследований: Научные публикации в периодических изданиях › Обзорная статья › Рецензирование
Diazocarbonyl and Related Compounds in the Synthesis of Azoles. / Budeev, Anton; Kantin, Grigory; Dar'in, Dmitry; Krasavin, Mikhail.
в: Molecules (Basel, Switzerland), Том 26, № 9, 2530, 05.2021.Результаты исследований: Научные публикации в периодических изданиях › Обзорная статья › Рецензирование
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TY - JOUR
T1 - Diazocarbonyl and Related Compounds in the Synthesis of Azoles
AU - Budeev, Anton
AU - Kantin, Grigory
AU - Dar'in, Dmitry
AU - Krasavin, Mikhail
N1 - Publisher Copyright: © 2021 by the authors. Licensee MDPI, Basel, Switzerland.
PY - 2021/5
Y1 - 2021/5
N2 - Diazocarbonyl compounds have found numerous applications in many areas of chemistry. Among the most developed fields of diazo chemistry is the preparation of azoles from diazo compounds. This approach represents a useful alternative to more conventional methods of the synthesis of azoles. A comprehensive review on the preparation of various azoles (oxazoles, thiazoles, imidazoles, pyrazoles, triazoles, and tetrazoles) from diazocarbonyl and related compounds is presented for the first time along with discussion of advantages and disadvantages of «diazo» approaches to azoles.
AB - Diazocarbonyl compounds have found numerous applications in many areas of chemistry. Among the most developed fields of diazo chemistry is the preparation of azoles from diazo compounds. This approach represents a useful alternative to more conventional methods of the synthesis of azoles. A comprehensive review on the preparation of various azoles (oxazoles, thiazoles, imidazoles, pyrazoles, triazoles, and tetrazoles) from diazocarbonyl and related compounds is presented for the first time along with discussion of advantages and disadvantages of «diazo» approaches to azoles.
KW - atom economy
KW - azoles
KW - diazocarbonyl compounds
KW - CASCADE CYCLIZATION REACTIONS
KW - ONE-POT SYNTHESIS
KW - AZIDE-FREE SYNTHESIS
KW - ALPHA-DIAZOKETONES
KW - H INSERTION REACTIONS
KW - REGIOSELECTIVE 3+2 CYCLOADDITION
KW - 1,3-DIPOLAR CYCLOADDITION
KW - DIAZO OXIME ETHERS
KW - TERT-BUTYL NITRITE
KW - METAL-FREE
KW - Azoles
KW - Diazocarbonyl compounds
KW - Atom economy
UR - http://www.scopus.com/inward/record.url?scp=85105199842&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/cbd41d7c-5f5b-3b97-a9e1-29756c949200/
U2 - 10.3390/molecules26092530
DO - 10.3390/molecules26092530
M3 - Review article
C2 - 33926128
AN - SCOPUS:85105199842
VL - 26
JO - Molecules
JF - Molecules
SN - 1420-3049
IS - 9
M1 - 2530
ER -
ID: 76894003