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Diazocarbonyl and Related Compounds in the Synthesis of Azoles. / Budeev, Anton; Kantin, Grigory; Dar'in, Dmitry; Krasavin, Mikhail.

в: Molecules (Basel, Switzerland), Том 26, № 9, 2530, 05.2021.

Результаты исследований: Научные публикации в периодических изданияхОбзорная статьяРецензирование

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@article{4144081f0395435fb15eee89bf6e4f7b,
title = "Diazocarbonyl and Related Compounds in the Synthesis of Azoles",
abstract = "Diazocarbonyl compounds have found numerous applications in many areas of chemistry. Among the most developed fields of diazo chemistry is the preparation of azoles from diazo compounds. This approach represents a useful alternative to more conventional methods of the synthesis of azoles. A comprehensive review on the preparation of various azoles (oxazoles, thiazoles, imidazoles, pyrazoles, triazoles, and tetrazoles) from diazocarbonyl and related compounds is presented for the first time along with discussion of advantages and disadvantages of «diazo» approaches to azoles.",
keywords = "atom economy, azoles, diazocarbonyl compounds, CASCADE CYCLIZATION REACTIONS, ONE-POT SYNTHESIS, AZIDE-FREE SYNTHESIS, ALPHA-DIAZOKETONES, H INSERTION REACTIONS, REGIOSELECTIVE 3+2 CYCLOADDITION, 1,3-DIPOLAR CYCLOADDITION, DIAZO OXIME ETHERS, TERT-BUTYL NITRITE, METAL-FREE, Azoles, Diazocarbonyl compounds, Atom economy",
author = "Anton Budeev and Grigory Kantin and Dmitry Dar'in and Mikhail Krasavin",
note = "Publisher Copyright: {\textcopyright} 2021 by the authors. Licensee MDPI, Basel, Switzerland.",
year = "2021",
month = may,
doi = "10.3390/molecules26092530",
language = "English",
volume = "26",
journal = "Molecules",
issn = "1420-3049",
publisher = "MDPI AG",
number = "9",

}

RIS

TY - JOUR

T1 - Diazocarbonyl and Related Compounds in the Synthesis of Azoles

AU - Budeev, Anton

AU - Kantin, Grigory

AU - Dar'in, Dmitry

AU - Krasavin, Mikhail

N1 - Publisher Copyright: © 2021 by the authors. Licensee MDPI, Basel, Switzerland.

PY - 2021/5

Y1 - 2021/5

N2 - Diazocarbonyl compounds have found numerous applications in many areas of chemistry. Among the most developed fields of diazo chemistry is the preparation of azoles from diazo compounds. This approach represents a useful alternative to more conventional methods of the synthesis of azoles. A comprehensive review on the preparation of various azoles (oxazoles, thiazoles, imidazoles, pyrazoles, triazoles, and tetrazoles) from diazocarbonyl and related compounds is presented for the first time along with discussion of advantages and disadvantages of «diazo» approaches to azoles.

AB - Diazocarbonyl compounds have found numerous applications in many areas of chemistry. Among the most developed fields of diazo chemistry is the preparation of azoles from diazo compounds. This approach represents a useful alternative to more conventional methods of the synthesis of azoles. A comprehensive review on the preparation of various azoles (oxazoles, thiazoles, imidazoles, pyrazoles, triazoles, and tetrazoles) from diazocarbonyl and related compounds is presented for the first time along with discussion of advantages and disadvantages of «diazo» approaches to azoles.

KW - atom economy

KW - azoles

KW - diazocarbonyl compounds

KW - CASCADE CYCLIZATION REACTIONS

KW - ONE-POT SYNTHESIS

KW - AZIDE-FREE SYNTHESIS

KW - ALPHA-DIAZOKETONES

KW - H INSERTION REACTIONS

KW - REGIOSELECTIVE 3+2 CYCLOADDITION

KW - 1,3-DIPOLAR CYCLOADDITION

KW - DIAZO OXIME ETHERS

KW - TERT-BUTYL NITRITE

KW - METAL-FREE

KW - Azoles

KW - Diazocarbonyl compounds

KW - Atom economy

UR - http://www.scopus.com/inward/record.url?scp=85105199842&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/cbd41d7c-5f5b-3b97-a9e1-29756c949200/

U2 - 10.3390/molecules26092530

DO - 10.3390/molecules26092530

M3 - Review article

C2 - 33926128

AN - SCOPUS:85105199842

VL - 26

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 9

M1 - 2530

ER -

ID: 76894003