Determination of elements in viscous organic liquids by arc atomic emission spectrometry

Standard

Determination of elements in viscous organic liquids by arc atomic emission spectrometry. / Savinov, S. S. ; Zverkov, N. A. ; Drobyshev, A. I. .

в: Journal of Applied Spectroscopy, Том 89, № 6, 27.01.2023, стр. 1015-1020.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{5c500015a38a487192003c4bd1e4672d,

title = "Determination of elements in viscous organic liquids by arc atomic emission spectrometry",

abstract = "Direct analysis of viscous organic liquids (medical and industrial adhesives, polymeric flocculant) by arc atomic emission spectrometry using aqueous standard solutions for constructing calibration dependences is shown to be impossible due to a matrix effect. This limitation is eliminated when the samples are diluted by at least an order of magnitude, which leads to an increase in the detection limits. A simplified scheme of acid mineralization of samples directly on the electrode (50 μL of HNO3 per 10 μL of sample) is proposed. The absence of a matrix effect is confirmed by calculation of the plasma parameters and comparison with results obtained after traditional acid decomposition. The proposed method can produce in a short time information on the content of a set of elements (Ag, Al, B, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, P. Pb, Ti, V, Zn) from hundredths of a mg/kg in viscous organic liquids.",

keywords = "atomic emission spectrometry, arc discharge, Dry residue, matrix effects, Acid mineralization, Electrode mineralization, Adhesives, Flocculants, Atomic emission spectrometry, Matrix effect, Arc discharge",

author = "Savinov, {S. S.} and Zverkov, {N. A.} and Drobyshev, {A. I.}",

note = "Savinov S. S., Zverkov N. A., Drobyshev A. I. Determination of elements in viscous organic liquids by arc atomic emission spectrometry // Journal of Applied Spectroscopy. 2023, v. 89, is. 6, p. 1015-1020",

year = "2023",

month = jan,

day = "27",

doi = "10.1007/s10812-023-01460-7",

language = "English",

volume = "89",

pages = "1015--1020",

journal = "Journal of Applied Spectroscopy (English Translation of Zhurnal Prikladnoi Spektroskopii)",

issn = "0021-9037",

publisher = "Springer Nature",

number = "6",

}

RIS

TY - JOUR

T1 - Determination of elements in viscous organic liquids by arc atomic emission spectrometry

AU - Savinov, S. S.

AU - Zverkov, N. A.

AU - Drobyshev, A. I.

N1 - Savinov S. S., Zverkov N. A., Drobyshev A. I. Determination of elements in viscous organic liquids by arc atomic emission spectrometry // Journal of Applied Spectroscopy. 2023, v. 89, is. 6, p. 1015-1020

PY - 2023/1/27

Y1 - 2023/1/27

N2 - Direct analysis of viscous organic liquids (medical and industrial adhesives, polymeric flocculant) by arc atomic emission spectrometry using aqueous standard solutions for constructing calibration dependences is shown to be impossible due to a matrix effect. This limitation is eliminated when the samples are diluted by at least an order of magnitude, which leads to an increase in the detection limits. A simplified scheme of acid mineralization of samples directly on the electrode (50 μL of HNO3 per 10 μL of sample) is proposed. The absence of a matrix effect is confirmed by calculation of the plasma parameters and comparison with results obtained after traditional acid decomposition. The proposed method can produce in a short time information on the content of a set of elements (Ag, Al, B, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, P. Pb, Ti, V, Zn) from hundredths of a mg/kg in viscous organic liquids.

AB - Direct analysis of viscous organic liquids (medical and industrial adhesives, polymeric flocculant) by arc atomic emission spectrometry using aqueous standard solutions for constructing calibration dependences is shown to be impossible due to a matrix effect. This limitation is eliminated when the samples are diluted by at least an order of magnitude, which leads to an increase in the detection limits. A simplified scheme of acid mineralization of samples directly on the electrode (50 μL of HNO3 per 10 μL of sample) is proposed. The absence of a matrix effect is confirmed by calculation of the plasma parameters and comparison with results obtained after traditional acid decomposition. The proposed method can produce in a short time information on the content of a set of elements (Ag, Al, B, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, P. Pb, Ti, V, Zn) from hundredths of a mg/kg in viscous organic liquids.

KW - atomic emission spectrometry

KW - arc discharge

KW - Dry residue

KW - matrix effects

KW - Acid mineralization

KW - Electrode mineralization

KW - Adhesives

KW - Flocculants

KW - Atomic emission spectrometry

KW - Matrix effect

KW - Arc discharge

UR - https://www.mendeley.com/catalogue/19ff3101-eab1-33e0-885b-e22fef93d8d3/

U2 - 10.1007/s10812-023-01460-7

DO - 10.1007/s10812-023-01460-7

M3 - Article

VL - 89

SP - 1015

EP - 1020

JO - Journal of Applied Spectroscopy (English Translation of Zhurnal Prikladnoi Spektroskopii)

JF - Journal of Applied Spectroscopy (English Translation of Zhurnal Prikladnoi Spektroskopii)

SN - 0021-9037

IS - 6

ER -

ID: 102428099