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Dendritic Spherical Polymer Brushes: Theory and Self-Consistent Field Modeling. / Rud, Oleg V.; Polotsky, Alexey A.; Gillich, Torben; Borisov, Oleg V.; Leermakers, Frans A. M.; Textor, Marcus; Birshtein, Tatiana M.

в: Macromolecules, Том 46, № 11, 2013, стр. 4651-4662.

Результаты исследований: Научные публикации в периодических изданиях › статья

Harvard

Rud, OV, Polotsky, AA, Gillich, T, Borisov, OV, Leermakers, FAM, Textor, M & Birshtein, TM 2013, 'Dendritic Spherical Polymer Brushes: Theory and Self-Consistent Field Modeling', Macromolecules, Том. 46, № 11, стр. 4651-4662. https://doi.org/10.1021/ma302632b

APA

Rud, O. V., Polotsky, A. A., Gillich, T., Borisov, O. V., Leermakers, F. A. M., Textor, M., & Birshtein, T. M. (2013). Dendritic Spherical Polymer Brushes: Theory and Self-Consistent Field Modeling. Macromolecules, 46(11), 4651-4662. https://doi.org/10.1021/ma302632b

Vancouver

Rud OV, Polotsky AA, Gillich T, Borisov OV, Leermakers FAM, Textor M и пр. Dendritic Spherical Polymer Brushes: Theory and Self-Consistent Field Modeling. Macromolecules. 2013;46(11):4651-4662. https://doi.org/10.1021/ma302632b

Author

Rud, Oleg V. ; Polotsky, Alexey A. ; Gillich, Torben ; Borisov, Oleg V. ; Leermakers, Frans A. M. ; Textor, Marcus ; Birshtein, Tatiana M. / Dendritic Spherical Polymer Brushes: Theory and Self-Consistent Field Modeling. в: Macromolecules. 2013 ; Том 46, № 11. стр. 4651-4662.

BibTeX

@article{783b7bd374f54c5299127db688052a15,
title = "Dendritic Spherical Polymer Brushes: Theory and Self-Consistent Field Modeling",
abstract = "Equilibrium structural properties of polymer brushes formed by dendrons grafted via the root segment onto spherical surfaces (dendritic spherical polymer brushes, DSPB) are studied by means of the Scheutjens-Fleer self consistent field (SF-SCF) numerical approach and scaling analysis. In particular, we focus on the effects of the variable curvature of the surface on the polymer volume fraction distribution and extension of the individual dendrons in DSPB. A systematic comparison with spherical polymer brushes formed by linear polymer chains (LSPB) end grafted to the surfaces of the same curvature radii is performed. We demonstrate that the difference in internal structural organization of DSPB and LSPB is most pronounced at small curvature radius of the grafting surface. In particular, the radial distribution of polymer volume fraction in DSPB is close to uniform, whereas in LSPB it decays in the radial direction following a power law. The quasi-plateau polymer volume fraction distribution in DSPB is ensured",
author = "Rud, {Oleg V.} and Polotsky, {Alexey A.} and Torben Gillich and Borisov, {Oleg V.} and Leermakers, {Frans A. M.} and Marcus Textor and Birshtein, {Tatiana M.}",
year = "2013",
doi = "10.1021/ma302632b",
language = "English",
volume = "46",
pages = "4651--4662",
journal = "Macromolecules",
issn = "0024-9297",
publisher = "American Chemical Society",
number = "11",

}

RIS

TY - JOUR

T1 - Dendritic Spherical Polymer Brushes: Theory and Self-Consistent Field Modeling

AU - Rud, Oleg V.

AU - Polotsky, Alexey A.

AU - Gillich, Torben

AU - Borisov, Oleg V.

AU - Leermakers, Frans A. M.

AU - Textor, Marcus

AU - Birshtein, Tatiana M.

PY - 2013

Y1 - 2013

N2 - Equilibrium structural properties of polymer brushes formed by dendrons grafted via the root segment onto spherical surfaces (dendritic spherical polymer brushes, DSPB) are studied by means of the Scheutjens-Fleer self consistent field (SF-SCF) numerical approach and scaling analysis. In particular, we focus on the effects of the variable curvature of the surface on the polymer volume fraction distribution and extension of the individual dendrons in DSPB. A systematic comparison with spherical polymer brushes formed by linear polymer chains (LSPB) end grafted to the surfaces of the same curvature radii is performed. We demonstrate that the difference in internal structural organization of DSPB and LSPB is most pronounced at small curvature radius of the grafting surface. In particular, the radial distribution of polymer volume fraction in DSPB is close to uniform, whereas in LSPB it decays in the radial direction following a power law. The quasi-plateau polymer volume fraction distribution in DSPB is ensured

AB - Equilibrium structural properties of polymer brushes formed by dendrons grafted via the root segment onto spherical surfaces (dendritic spherical polymer brushes, DSPB) are studied by means of the Scheutjens-Fleer self consistent field (SF-SCF) numerical approach and scaling analysis. In particular, we focus on the effects of the variable curvature of the surface on the polymer volume fraction distribution and extension of the individual dendrons in DSPB. A systematic comparison with spherical polymer brushes formed by linear polymer chains (LSPB) end grafted to the surfaces of the same curvature radii is performed. We demonstrate that the difference in internal structural organization of DSPB and LSPB is most pronounced at small curvature radius of the grafting surface. In particular, the radial distribution of polymer volume fraction in DSPB is close to uniform, whereas in LSPB it decays in the radial direction following a power law. The quasi-plateau polymer volume fraction distribution in DSPB is ensured

U2 - 10.1021/ma302632b

DO - 10.1021/ma302632b

M3 - Article

VL - 46

SP - 4651

EP - 4662

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 11

ER -

ID: 5695218