Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
The FTIR spectra of fluoroform trapped in argon and nitrogen matrixes are studied at T 10-30 K. The bands of E symmetry show the splitting effect in a nitrogen matrix, which is absent in an argon matrix. The effect is the most prominent in the case of the μ4 CH bending vibration. It decreases slightly with increasing temperature. Both static and Car-Parrinello molecular dynamic simulations suggest that the degeneracy lifting is due to C3v symmetry lowering caused by interactions between fluoroform and all neighbor N2 matrix molecules.
Язык оригинала | английский |
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Страницы (с-по) | 3497-3503 |
Число страниц | 7 |
Журнал | Journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment & general theory |
Том | 120 |
Номер выпуска | 20 |
DOI | |
Состояние | Опубликовано - 26 мая 2016 |
ID: 7568456