Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
c-X laser excitation spectrum of the Hg–Ar vdW complex. / Amano, K; Ohmori, K; Kurosawa, T; Chiba, H; Okunishi, M; Ueda, K; Sato, Y; Devdariani, AZ; Nikitin, EE.
в: Journal of Chemical Physics, Том 108, № 19, 15.05.1998, стр. 8110-8113.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - c-X laser excitation spectrum of the Hg–Ar vdW complex
AU - Amano, K
AU - Ohmori, K
AU - Kurosawa, T
AU - Chiba, H
AU - Okunishi, M
AU - Ueda, K
AU - Sato, Y
AU - Devdariani, AZ
AU - Nikitin, EE
PY - 1998/5/15
Y1 - 1998/5/15
N2 - We have measured the c(upsilon'=0-8)-X(upsilon=0) laser excitation spectrum of the Hg-Ar van der Waals complex. This corresponds to the first observation of the bound Hg-rare-gas complex in the dark c state. In this measurement, we employ the sequence of two laser pulses; the complex is excited by the first one to the dark bound level in the c state and then successively excited by the second one to another bright state for the optical detection. The Birge-Sponer (BS) plot of the upsilon' progression is well fitted by a straight line, suggesting that the c-state potential curve of Hg-Ar is well approximated by the Morse function. The linear fitting of this BS plot gives the potential parameters for the c state. (C) 1998 American Institute of Physics.
AB - We have measured the c(upsilon'=0-8)-X(upsilon=0) laser excitation spectrum of the Hg-Ar van der Waals complex. This corresponds to the first observation of the bound Hg-rare-gas complex in the dark c state. In this measurement, we employ the sequence of two laser pulses; the complex is excited by the first one to the dark bound level in the c state and then successively excited by the second one to another bright state for the optical detection. The Birge-Sponer (BS) plot of the upsilon' progression is well fitted by a straight line, suggesting that the c-state potential curve of Hg-Ar is well approximated by the Morse function. The linear fitting of this BS plot gives the potential parameters for the c state. (C) 1998 American Institute of Physics.
KW - SUPERSONIC JET
KW - INTERATOMIC POTENTIALS
KW - STATES
KW - SPECTROSCOPY
KW - MOLECULES
KW - DIMERS
KW - XENON
U2 - 10.1063/1.476250
DO - 10.1063/1.476250
M3 - статья
VL - 108
SP - 8110
EP - 8113
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 19
ER -
ID: 74053109