Результаты исследований: Публикации в книгах, отчётах, сборниках, трудах конференций › статья в сборнике материалов конференции › научная › Рецензирование
CVD of group 13-15 binary materials : Importance of the association reactions in the gas phase. / Timoshkin, AY.
FUNDAMENTAL GAS-PHASE AND SURFACE CHEMISTRY OF VAPOR-PHASE DEPOSITION II AND PROCESS CONTROL, DIAGNOSTICS, AND MODELING IN SEMICONDUCTOR MANFACTURING IV. ред. / MT Swihart; MD Allendorf; M Meyyappan. The Electrochemical Society, 2001. стр. 25-32 (Electrochemical Society Series; Том 2001).Результаты исследований: Публикации в книгах, отчётах, сборниках, трудах конференций › статья в сборнике материалов конференции › научная › Рецензирование
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TY - GEN
T1 - CVD of group 13-15 binary materials
AU - Timoshkin, AY
PY - 2001
Y1 - 2001
N2 - Geometries, vibrational frequencies and thermodynamic properties of trimeric rings [XMYH](3) and tetrameric clusters [XMYH](4), X=H,F,Cl,Br,l; M=Al,Ga,In; Y=N,P,As have been obtained at B3LY-P/LAN-L2DZP level of theory. Thermodynamic analysis of the oligomerization reactions shows that formation of cluster species in the gas phase is thermodynamically favorable in case of X=H. Furthermore, gas-phase generation of hexamer species [HMYH](6) should also be viable. Nitrogen-containing oligomers are highly stable in respect to dissociation, which makes them promising candidates for the stoichiometry controlled CVD of doped nitrides.
AB - Geometries, vibrational frequencies and thermodynamic properties of trimeric rings [XMYH](3) and tetrameric clusters [XMYH](4), X=H,F,Cl,Br,l; M=Al,Ga,In; Y=N,P,As have been obtained at B3LY-P/LAN-L2DZP level of theory. Thermodynamic analysis of the oligomerization reactions shows that formation of cluster species in the gas phase is thermodynamically favorable in case of X=H. Furthermore, gas-phase generation of hexamer species [HMYH](6) should also be viable. Nitrogen-containing oligomers are highly stable in respect to dissociation, which makes them promising candidates for the stoichiometry controlled CVD of doped nitrides.
KW - CHEMICAL-VAPOR-DEPOSITION
KW - SURFACE-CHEMISTRY
KW - STABILITIES
KW - AROMATICITY
KW - ENERGETICS
KW - ATOMS
KW - AL
M3 - статья в сборнике материалов конференции
SN - 1-56677-319-9
T3 - Electrochemical Society Series
SP - 25
EP - 32
BT - FUNDAMENTAL GAS-PHASE AND SURFACE CHEMISTRY OF VAPOR-PHASE DEPOSITION II AND PROCESS CONTROL, DIAGNOSTICS, AND MODELING IN SEMICONDUCTOR MANFACTURING IV
A2 - Swihart, MT
A2 - Allendorf, MD
A2 - Meyyappan, M
PB - The Electrochemical Society
Y2 - 26 March 2001
ER -
ID: 85941759