Cu(II) pentaiodobenzoate complexes › Научные исследования в СПбГУ

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Cu(II) pentaiodobenzoate complexes : “super heavy carboxylates” featuring strong halogen bonding. / Bondarenko, Mikhail A.; Abramov, Pavel A.; Novikov, Alexander S.; Sokolov, Maxim N.; Adonin, Sergey A.

в: Polyhedron, Том 214, 115644, 01.03.2022.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

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Bondarenko, Mikhail A. ; Abramov, Pavel A. ; Novikov, Alexander S. ; Sokolov, Maxim N. ; Adonin, Sergey A. / Cu(II) pentaiodobenzoate complexes : “super heavy carboxylates” featuring strong halogen bonding. в: Polyhedron. 2022 ; Том 214.

BibTeX

@article{37d91bfab536498c8c71d2790bdddb43,

title = "Cu(II) pentaiodobenzoate complexes: “super heavy carboxylates” featuring strong halogen bonding",

abstract = "The first heteroleptic pentaiodobenzoate (PIBA) metal complexes [Cu(PIBA)2L2] (L = Py (1), 3,5-MePy (2), 2,6-MePy (3)) and [Cu(PIBA)2(4-MePy)(DMF)1.5(H2O)0.5]·2DMF (4) were prepared and characterized. In most cases, there are multiple strong halogen bonds and Type I halogen···halogen interactions in their structures; the energies of these contacts were estimated by theoretical methods. Thermal stability of 1–4 was studied by thermogravimetric analysis.",

keywords = "Carboxylates, Complexes, Copper, Halogen bonding, Non-covalent interactions, STABILIZATION, CRYSTAL-STRUCTURES, SOLID-STATE, TRANSITION, LIGANDS, MOLECULAR-COMPLEXES, HEXAFLUOROACETYLACETONATE, MAGNETIC-PROPERTIES, COORDINATION POLYMERS, METAL-COMPLEXES",

author = "Bondarenko, {Mikhail A.} and Abramov, {Pavel A.} and Novikov, {Alexander S.} and Sokolov, {Maxim N.} and Adonin, {Sergey A.}",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Ltd",

year = "2022",

month = mar,

day = "1",

doi = "10.1016/j.poly.2021.115644",

language = "English",

volume = "214",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Cu(II) pentaiodobenzoate complexes

T2 - “super heavy carboxylates” featuring strong halogen bonding

AU - Bondarenko, Mikhail A.

AU - Abramov, Pavel A.

AU - Novikov, Alexander S.

AU - Sokolov, Maxim N.

AU - Adonin, Sergey A.

PY - 2022/3/1

Y1 - 2022/3/1

N2 - The first heteroleptic pentaiodobenzoate (PIBA) metal complexes [Cu(PIBA)2L2] (L = Py (1), 3,5-MePy (2), 2,6-MePy (3)) and [Cu(PIBA)2(4-MePy)(DMF)1.5(H2O)0.5]·2DMF (4) were prepared and characterized. In most cases, there are multiple strong halogen bonds and Type I halogen···halogen interactions in their structures; the energies of these contacts were estimated by theoretical methods. Thermal stability of 1–4 was studied by thermogravimetric analysis.

AB - The first heteroleptic pentaiodobenzoate (PIBA) metal complexes [Cu(PIBA)2L2] (L = Py (1), 3,5-MePy (2), 2,6-MePy (3)) and [Cu(PIBA)2(4-MePy)(DMF)1.5(H2O)0.5]·2DMF (4) were prepared and characterized. In most cases, there are multiple strong halogen bonds and Type I halogen···halogen interactions in their structures; the energies of these contacts were estimated by theoretical methods. Thermal stability of 1–4 was studied by thermogravimetric analysis.

KW - Carboxylates

KW - Complexes

KW - Copper

KW - Halogen bonding

KW - Non-covalent interactions

KW - STABILIZATION

KW - CRYSTAL-STRUCTURES

KW - SOLID-STATE

KW - TRANSITION

KW - LIGANDS

KW - MOLECULAR-COMPLEXES

KW - HEXAFLUOROACETYLACETONATE

KW - MAGNETIC-PROPERTIES

KW - COORDINATION POLYMERS

KW - METAL-COMPLEXES

UR - http://www.scopus.com/inward/record.url?scp=85122290895&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2021.115644

DO - 10.1016/j.poly.2021.115644

M3 - Article

AN - SCOPUS:85122290895

VL - 214

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

M1 - 115644

ER -

ID: 94491829

Cu(II) pentaiodobenzoate complexes: “super heavy carboxylates” featuring strong halogen bonding

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