Standard

Crystal structure, thermal and compositional deformations of β-CsB5O8. / Bubnova, R.; Dinnebier, R. E.; Filatov, S.; Anderson, J.

в: Crystal Research and Technology, Том 42, № 2, 01.02.2007, стр. 143-150.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Bubnova, R, Dinnebier, RE, Filatov, S & Anderson, J 2007, 'Crystal structure, thermal and compositional deformations of β-CsB5O8', Crystal Research and Technology, Том. 42, № 2, стр. 143-150. https://doi.org/10.1002/crat.200610787

APA

Bubnova, R., Dinnebier, R. E., Filatov, S., & Anderson, J. (2007). Crystal structure, thermal and compositional deformations of β-CsB5O8. Crystal Research and Technology, 42(2), 143-150. https://doi.org/10.1002/crat.200610787

Vancouver

Bubnova R, Dinnebier RE, Filatov S, Anderson J. Crystal structure, thermal and compositional deformations of β-CsB5O8. Crystal Research and Technology. 2007 Февр. 1;42(2):143-150. https://doi.org/10.1002/crat.200610787

Author

Bubnova, R. ; Dinnebier, R. E. ; Filatov, S. ; Anderson, J. / Crystal structure, thermal and compositional deformations of β-CsB5O8. в: Crystal Research and Technology. 2007 ; Том 42, № 2. стр. 143-150.

BibTeX

@article{9e4cbe5e82a948159238ae1b6dc90fc0,
title = "Crystal structure, thermal and compositional deformations of β-CsB5O8",
abstract = "The crystal structure of β-CsB5O8 has been determined from X-ray powder diffraction data using synchrotron radiation: Pbca, a=7.8131(3) {\AA}, b=12.0652(4) {\AA}, c=14.9582(4) {\AA}, Z=8, ρcalc = 2.967 g/cm3, R-p=0.076, R-wp=0.094. β-CsB5O8 was found to be isostructural with β-KB5O8 and P-RbB5O8. The crystal structure consists of a double interlocking framework built up from B-O pentaborate groups. The crystal structure exhibits a highly anisotropic thermal expansion: αa=53, αb=16, αc= 14.10-6/K; the anisotropy may be caused by partial straightening of the screw chains of the pentaborate groups. The similarity of the thermal and compositional (Cs-Rb-K substitution) deformations CsB5O8 is revealed: increasing the radius of the metal by 0.01 {\AA} leads to the same deformations of the crystal structure as increasing the temperature by 35°C.",
keywords = "Cesium pentaborate, Compositional deformation, Crystal structure, Rietveld refinement, Thermal expansion",
author = "R. Bubnova and Dinnebier, {R. E.} and S. Filatov and J. Anderson",
year = "2007",
month = feb,
day = "1",
doi = "10.1002/crat.200610787",
language = "English",
volume = "42",
pages = "143--150",
journal = "Crystal Research and Technology",
issn = "0232-1300",
publisher = "Wiley-Blackwell",
number = "2",

}

RIS

TY - JOUR

T1 - Crystal structure, thermal and compositional deformations of β-CsB5O8

AU - Bubnova, R.

AU - Dinnebier, R. E.

AU - Filatov, S.

AU - Anderson, J.

PY - 2007/2/1

Y1 - 2007/2/1

N2 - The crystal structure of β-CsB5O8 has been determined from X-ray powder diffraction data using synchrotron radiation: Pbca, a=7.8131(3) Å, b=12.0652(4) Å, c=14.9582(4) Å, Z=8, ρcalc = 2.967 g/cm3, R-p=0.076, R-wp=0.094. β-CsB5O8 was found to be isostructural with β-KB5O8 and P-RbB5O8. The crystal structure consists of a double interlocking framework built up from B-O pentaborate groups. The crystal structure exhibits a highly anisotropic thermal expansion: αa=53, αb=16, αc= 14.10-6/K; the anisotropy may be caused by partial straightening of the screw chains of the pentaborate groups. The similarity of the thermal and compositional (Cs-Rb-K substitution) deformations CsB5O8 is revealed: increasing the radius of the metal by 0.01 Å leads to the same deformations of the crystal structure as increasing the temperature by 35°C.

AB - The crystal structure of β-CsB5O8 has been determined from X-ray powder diffraction data using synchrotron radiation: Pbca, a=7.8131(3) Å, b=12.0652(4) Å, c=14.9582(4) Å, Z=8, ρcalc = 2.967 g/cm3, R-p=0.076, R-wp=0.094. β-CsB5O8 was found to be isostructural with β-KB5O8 and P-RbB5O8. The crystal structure consists of a double interlocking framework built up from B-O pentaborate groups. The crystal structure exhibits a highly anisotropic thermal expansion: αa=53, αb=16, αc= 14.10-6/K; the anisotropy may be caused by partial straightening of the screw chains of the pentaborate groups. The similarity of the thermal and compositional (Cs-Rb-K substitution) deformations CsB5O8 is revealed: increasing the radius of the metal by 0.01 Å leads to the same deformations of the crystal structure as increasing the temperature by 35°C.

KW - Cesium pentaborate

KW - Compositional deformation

KW - Crystal structure

KW - Rietveld refinement

KW - Thermal expansion

UR - http://www.scopus.com/inward/record.url?scp=34547502698&partnerID=8YFLogxK

U2 - 10.1002/crat.200610787

DO - 10.1002/crat.200610787

M3 - Article

AN - SCOPUS:34547502698

VL - 42

SP - 143

EP - 150

JO - Crystal Research and Technology

JF - Crystal Research and Technology

SN - 0232-1300

IS - 2

ER -

ID: 53950861