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Crystal structure, raman spectroscopy and dielectric properties of new semiorganic crystals based on 2-methylbenzimidazole. / Balashova, E. V.; Svinarev, F. B.; Zolotarev, A. A.; Levin, A. A.; Brunkov, P. N.; Davydov, V. Yu; Smirnov, A. N.; Redkov, A. V.; Pankova, G. A.; Krichevtsov, B. B.

в: Crystals, Том 9, № 11, 573, 11.2019.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Balashova, EV, Svinarev, FB, Zolotarev, AA, Levin, AA, Brunkov, PN, Davydov, VY, Smirnov, AN, Redkov, AV, Pankova, GA & Krichevtsov, BB 2019, 'Crystal structure, raman spectroscopy and dielectric properties of new semiorganic crystals based on 2-methylbenzimidazole', Crystals, Том. 9, № 11, 573. https://doi.org/10.3390/cryst9110573

APA

Balashova, E. V., Svinarev, F. B., Zolotarev, A. A., Levin, A. A., Brunkov, P. N., Davydov, V. Y., Smirnov, A. N., Redkov, A. V., Pankova, G. A., & Krichevtsov, B. B. (2019). Crystal structure, raman spectroscopy and dielectric properties of new semiorganic crystals based on 2-methylbenzimidazole. Crystals, 9(11), [573]. https://doi.org/10.3390/cryst9110573

Vancouver

Balashova EV, Svinarev FB, Zolotarev AA, Levin AA, Brunkov PN, Davydov VY и пр. Crystal structure, raman spectroscopy and dielectric properties of new semiorganic crystals based on 2-methylbenzimidazole. Crystals. 2019 Нояб.;9(11). 573. https://doi.org/10.3390/cryst9110573

Author

Balashova, E. V. ; Svinarev, F. B. ; Zolotarev, A. A. ; Levin, A. A. ; Brunkov, P. N. ; Davydov, V. Yu ; Smirnov, A. N. ; Redkov, A. V. ; Pankova, G. A. ; Krichevtsov, B. B. / Crystal structure, raman spectroscopy and dielectric properties of new semiorganic crystals based on 2-methylbenzimidazole. в: Crystals. 2019 ; Том 9, № 11.

BibTeX

@article{6c8b5a3fdb354c0eb428a7e0d030260e,
title = "Crystal structure, raman spectroscopy and dielectric properties of new semiorganic crystals based on 2-methylbenzimidazole",
abstract = "New single crystals, based on 2-methylbenzimidazole (MBI), of MBI-phosphite (C16 H24 N4 O7 P2), MBI-phosphate-1 (C16 H24 N4 O9 P2), and MBI-phosphate-2 (C8 H16 N2 O9 P2) were obtained by slow evaporation method from a mixture of alcohol solution of MBI crystals and water solution of phosphorous or phosphoric acids. Crystal structures and chemical compositions were determined by single crystal X-ray diffraction (XRD) analysis and confirmed by XRD of powders and elemental analysis. Raman spectroscopy of new crystals evidences the presence in crystals of MBI-, H3 PO3-, or H3 PO4-and water molecules. Dielectric properties of crystals reveal strong increase and low frequency dispersion of dielectric constant and losses at heating, indicating the appearance of proton conductivity. At low temperatures in MBI-phosphate-2, an increase of dielectric constant analogous to quantum paraelectric state is observed.",
keywords = "Crystal growth, Crystal structure, Dielectric properties, Hydrogen bonds, Proton conductivity, Raman spectroscopy, Semiorganic crystals, XRD",
author = "Balashova, {E. V.} and Svinarev, {F. B.} and Zolotarev, {A. A.} and Levin, {A. A.} and Brunkov, {P. N.} and Davydov, {V. Yu} and Smirnov, {A. N.} and Redkov, {A. V.} and Pankova, {G. A.} and Krichevtsov, {B. B.}",
year = "2019",
month = nov,
doi = "10.3390/cryst9110573",
language = "English",
volume = "9",
journal = "Liquid Crystals Today",
issn = "1358-314X",
publisher = "MDPI AG",
number = "11",

}

RIS

TY - JOUR

T1 - Crystal structure, raman spectroscopy and dielectric properties of new semiorganic crystals based on 2-methylbenzimidazole

AU - Balashova, E. V.

AU - Svinarev, F. B.

AU - Zolotarev, A. A.

AU - Levin, A. A.

AU - Brunkov, P. N.

AU - Davydov, V. Yu

AU - Smirnov, A. N.

AU - Redkov, A. V.

AU - Pankova, G. A.

AU - Krichevtsov, B. B.

PY - 2019/11

Y1 - 2019/11

N2 - New single crystals, based on 2-methylbenzimidazole (MBI), of MBI-phosphite (C16 H24 N4 O7 P2), MBI-phosphate-1 (C16 H24 N4 O9 P2), and MBI-phosphate-2 (C8 H16 N2 O9 P2) were obtained by slow evaporation method from a mixture of alcohol solution of MBI crystals and water solution of phosphorous or phosphoric acids. Crystal structures and chemical compositions were determined by single crystal X-ray diffraction (XRD) analysis and confirmed by XRD of powders and elemental analysis. Raman spectroscopy of new crystals evidences the presence in crystals of MBI-, H3 PO3-, or H3 PO4-and water molecules. Dielectric properties of crystals reveal strong increase and low frequency dispersion of dielectric constant and losses at heating, indicating the appearance of proton conductivity. At low temperatures in MBI-phosphate-2, an increase of dielectric constant analogous to quantum paraelectric state is observed.

AB - New single crystals, based on 2-methylbenzimidazole (MBI), of MBI-phosphite (C16 H24 N4 O7 P2), MBI-phosphate-1 (C16 H24 N4 O9 P2), and MBI-phosphate-2 (C8 H16 N2 O9 P2) were obtained by slow evaporation method from a mixture of alcohol solution of MBI crystals and water solution of phosphorous or phosphoric acids. Crystal structures and chemical compositions were determined by single crystal X-ray diffraction (XRD) analysis and confirmed by XRD of powders and elemental analysis. Raman spectroscopy of new crystals evidences the presence in crystals of MBI-, H3 PO3-, or H3 PO4-and water molecules. Dielectric properties of crystals reveal strong increase and low frequency dispersion of dielectric constant and losses at heating, indicating the appearance of proton conductivity. At low temperatures in MBI-phosphate-2, an increase of dielectric constant analogous to quantum paraelectric state is observed.

KW - Crystal growth

KW - Crystal structure

KW - Dielectric properties

KW - Hydrogen bonds

KW - Proton conductivity

KW - Raman spectroscopy

KW - Semiorganic crystals

KW - XRD

UR - http://www.scopus.com/inward/record.url?scp=85074392795&partnerID=8YFLogxK

U2 - 10.3390/cryst9110573

DO - 10.3390/cryst9110573

M3 - Article

AN - SCOPUS:85074392795

VL - 9

JO - Liquid Crystals Today

JF - Liquid Crystals Today

SN - 1358-314X

IS - 11

M1 - 573

ER -

ID: 51465023