Standard

Crystal structure and thermal properties of the LixNa1–xKZnP2O7 solid solutions and its relation to the MM′ZnP2O7 diphosphate family. / Volkov, Sergey; Petrova, Maya; Sinel'shchikova, Olga; Firsova, Vera; Popova, Valentina; Ugolkov, Valery; Krzhizhanovskaya, Maria; Bubnova, Rimma.

в: Journal of Solid State Chemistry, Том 269, 01.01.2019, стр. 486-493.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Volkov, S, Petrova, M, Sinel'shchikova, O, Firsova, V, Popova, V, Ugolkov, V, Krzhizhanovskaya, M & Bubnova, R 2019, 'Crystal structure and thermal properties of the LixNa1–xKZnP2O7 solid solutions and its relation to the MM′ZnP2O7 diphosphate family', Journal of Solid State Chemistry, Том. 269, стр. 486-493. https://doi.org/10.1016/j.jssc.2018.10.029

APA

Volkov, S., Petrova, M., Sinel'shchikova, O., Firsova, V., Popova, V., Ugolkov, V., Krzhizhanovskaya, M., & Bubnova, R. (2019). Crystal structure and thermal properties of the LixNa1–xKZnP2O7 solid solutions and its relation to the MM′ZnP2O7 diphosphate family. Journal of Solid State Chemistry, 269, 486-493. https://doi.org/10.1016/j.jssc.2018.10.029

Vancouver

Volkov S, Petrova M, Sinel'shchikova O, Firsova V, Popova V, Ugolkov V и пр. Crystal structure and thermal properties of the LixNa1–xKZnP2O7 solid solutions and its relation to the MM′ZnP2O7 diphosphate family. Journal of Solid State Chemistry. 2019 Янв. 1;269:486-493. https://doi.org/10.1016/j.jssc.2018.10.029

Author

Volkov, Sergey ; Petrova, Maya ; Sinel'shchikova, Olga ; Firsova, Vera ; Popova, Valentina ; Ugolkov, Valery ; Krzhizhanovskaya, Maria ; Bubnova, Rimma. / Crystal structure and thermal properties of the LixNa1–xKZnP2O7 solid solutions and its relation to the MM′ZnP2O7 diphosphate family. в: Journal of Solid State Chemistry. 2019 ; Том 269. стр. 486-493.

BibTeX

@article{fb4769b38f034847a77899e43470245a,
title = "Crystal structure and thermal properties of the LixNa1–xKZnP2O7 solid solutions and its relation to the MM′ZnP2O7 diphosphate family",
abstract = "New solid solutions of LixNa1–xKZnP2O7 belonging to the MM'ZnP2O7 structural family (M = Li+, Na+, Zn2+; M{\textquoteright} = Na+, K+), were prepared and phase equilibria along the LiKZnP2O7–NaKZnP2O7 section were reported. These solid solutions were investigated single-crystal X-ray diffraction, high-temperature X-ray powder diffraction (HTXRD), differential scanning calorimetry, and impedance spectroscopy. A miscibility gap was found within the range of 0.8 < x < 1.0, and a binodal curve was constructed using HTXRD data. The similarity of the thermal and compositional deformation of LixNa1–xKZnP2O7 solid solutions is revealed: increasing the radius of the metal by 0.01 {\AA} leads to the same deformations of the crystal structure as increasing the temperature by 31 °C. The Li/Na↔Zn cation exchange lead to an increase in conductivity above 300 °C. The alkali mixed effect in activation energy occurs for LixNa1–xKZnP2O7 solid solutions near x = 0.5. The phase with the 2a×2b×c superstructure ordering was observed as a result of the solid solution melting.",
keywords = "Crystal structure, Phase relationships, Solid solutions, Zinc diphosphates",
author = "Sergey Volkov and Maya Petrova and Olga Sinel'shchikova and Vera Firsova and Valentina Popova and Valery Ugolkov and Maria Krzhizhanovskaya and Rimma Bubnova",
year = "2019",
month = jan,
day = "1",
doi = "10.1016/j.jssc.2018.10.029",
language = "English",
volume = "269",
pages = "486--493",
journal = "Journal of Solid State Chemistry",
issn = "0022-4596",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Crystal structure and thermal properties of the LixNa1–xKZnP2O7 solid solutions and its relation to the MM′ZnP2O7 diphosphate family

AU - Volkov, Sergey

AU - Petrova, Maya

AU - Sinel'shchikova, Olga

AU - Firsova, Vera

AU - Popova, Valentina

AU - Ugolkov, Valery

AU - Krzhizhanovskaya, Maria

AU - Bubnova, Rimma

PY - 2019/1/1

Y1 - 2019/1/1

N2 - New solid solutions of LixNa1–xKZnP2O7 belonging to the MM'ZnP2O7 structural family (M = Li+, Na+, Zn2+; M’ = Na+, K+), were prepared and phase equilibria along the LiKZnP2O7–NaKZnP2O7 section were reported. These solid solutions were investigated single-crystal X-ray diffraction, high-temperature X-ray powder diffraction (HTXRD), differential scanning calorimetry, and impedance spectroscopy. A miscibility gap was found within the range of 0.8 < x < 1.0, and a binodal curve was constructed using HTXRD data. The similarity of the thermal and compositional deformation of LixNa1–xKZnP2O7 solid solutions is revealed: increasing the radius of the metal by 0.01 Å leads to the same deformations of the crystal structure as increasing the temperature by 31 °C. The Li/Na↔Zn cation exchange lead to an increase in conductivity above 300 °C. The alkali mixed effect in activation energy occurs for LixNa1–xKZnP2O7 solid solutions near x = 0.5. The phase with the 2a×2b×c superstructure ordering was observed as a result of the solid solution melting.

AB - New solid solutions of LixNa1–xKZnP2O7 belonging to the MM'ZnP2O7 structural family (M = Li+, Na+, Zn2+; M’ = Na+, K+), were prepared and phase equilibria along the LiKZnP2O7–NaKZnP2O7 section were reported. These solid solutions were investigated single-crystal X-ray diffraction, high-temperature X-ray powder diffraction (HTXRD), differential scanning calorimetry, and impedance spectroscopy. A miscibility gap was found within the range of 0.8 < x < 1.0, and a binodal curve was constructed using HTXRD data. The similarity of the thermal and compositional deformation of LixNa1–xKZnP2O7 solid solutions is revealed: increasing the radius of the metal by 0.01 Å leads to the same deformations of the crystal structure as increasing the temperature by 31 °C. The Li/Na↔Zn cation exchange lead to an increase in conductivity above 300 °C. The alkali mixed effect in activation energy occurs for LixNa1–xKZnP2O7 solid solutions near x = 0.5. The phase with the 2a×2b×c superstructure ordering was observed as a result of the solid solution melting.

KW - Crystal structure

KW - Phase relationships

KW - Solid solutions

KW - Zinc diphosphates

UR - http://www.scopus.com/inward/record.url?scp=85055544594&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2018.10.029

DO - 10.1016/j.jssc.2018.10.029

M3 - Article

AN - SCOPUS:85055544594

VL - 269

SP - 486

EP - 493

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

ER -

ID: 35813625