Standard

Crystal structure and thermal behaviour of boropollucite CsBSi 2O6. / Bubnova, R. S.; Stepanov, N. K.; Levin, A. A.; Filatov, S. K.; Paufler, P.; Meyer, D. C.

в: Solid State Sciences, Том 6, № 7, 01.07.2004, стр. 629-637.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Bubnova, RS, Stepanov, NK, Levin, AA, Filatov, SK, Paufler, P & Meyer, DC 2004, 'Crystal structure and thermal behaviour of boropollucite CsBSi 2O6', Solid State Sciences, Том. 6, № 7, стр. 629-637. https://doi.org/10.1016/j.solidstatesciences.2004.03.015

APA

Bubnova, R. S., Stepanov, N. K., Levin, A. A., Filatov, S. K., Paufler, P., & Meyer, D. C. (2004). Crystal structure and thermal behaviour of boropollucite CsBSi 2O6. Solid State Sciences, 6(7), 629-637. https://doi.org/10.1016/j.solidstatesciences.2004.03.015

Vancouver

Bubnova RS, Stepanov NK, Levin AA, Filatov SK, Paufler P, Meyer DC. Crystal structure and thermal behaviour of boropollucite CsBSi 2O6. Solid State Sciences. 2004 Июль 1;6(7):629-637. https://doi.org/10.1016/j.solidstatesciences.2004.03.015

Author

Bubnova, R. S. ; Stepanov, N. K. ; Levin, A. A. ; Filatov, S. K. ; Paufler, P. ; Meyer, D. C. / Crystal structure and thermal behaviour of boropollucite CsBSi 2O6. в: Solid State Sciences. 2004 ; Том 6, № 7. стр. 629-637.

BibTeX

@article{f1512b7b1e174a9c889ec38aeebf72ac,
title = "Crystal structure and thermal behaviour of boropollucite CsBSi 2O6",
abstract = "The crystal structure of Cs0.82B1.09Si 1.98O6 boropollucite at room temperature was determined by direct methods and refined in the Ia{\=3}d space group using an anisotropic approximation of atomic thermal displacements (a=13.009 (1) {\AA}, Z=16, Rw=0.027, RF=0.037 for 141 independent observed (F≥4σF) reflections). The occupancy factors have been refined for Cs and tetrahedral positions assuming the oxygen sites being fully occupied. The compound is isostructural to leucite-pollucite high-temperature modification. Thermal behaviour of CsBSi2O6 was investigated by DTA and TG, annealing at different temperatures with following wet chemical analysis and high-temperature X-ray powder diffraction methods. The CsBSi2O6 cubic phase loses mass before melting and decomposes to form a new crystalline phase with close to CsBSi3O 8 stoichiometry in the temperature range of 1303-1353 K. Thermal expansion of two boropollucite samples, which differed in the number of Cs + and/or B3+ ions of a nominal composition CsBSi 2O6 was investigated in air as well as in vacuum. Temperature ranges of negative thermal expansion were found.",
keywords = "Boropollucite, Borosilicate, Crystal structure, Feldspar composition, Phase decomposition, Thermal expansion",
author = "Bubnova, {R. S.} and Stepanov, {N. K.} and Levin, {A. A.} and Filatov, {S. K.} and P. Paufler and Meyer, {D. C.}",
year = "2004",
month = jul,
day = "1",
doi = "10.1016/j.solidstatesciences.2004.03.015",
language = "English",
volume = "6",
pages = "629--637",
journal = "Solid State Sciences",
issn = "1293-2558",
publisher = "Elsevier",
number = "7",

}

RIS

TY - JOUR

T1 - Crystal structure and thermal behaviour of boropollucite CsBSi 2O6

AU - Bubnova, R. S.

AU - Stepanov, N. K.

AU - Levin, A. A.

AU - Filatov, S. K.

AU - Paufler, P.

AU - Meyer, D. C.

PY - 2004/7/1

Y1 - 2004/7/1

N2 - The crystal structure of Cs0.82B1.09Si 1.98O6 boropollucite at room temperature was determined by direct methods and refined in the Ia3̄d space group using an anisotropic approximation of atomic thermal displacements (a=13.009 (1) Å, Z=16, Rw=0.027, RF=0.037 for 141 independent observed (F≥4σF) reflections). The occupancy factors have been refined for Cs and tetrahedral positions assuming the oxygen sites being fully occupied. The compound is isostructural to leucite-pollucite high-temperature modification. Thermal behaviour of CsBSi2O6 was investigated by DTA and TG, annealing at different temperatures with following wet chemical analysis and high-temperature X-ray powder diffraction methods. The CsBSi2O6 cubic phase loses mass before melting and decomposes to form a new crystalline phase with close to CsBSi3O 8 stoichiometry in the temperature range of 1303-1353 K. Thermal expansion of two boropollucite samples, which differed in the number of Cs + and/or B3+ ions of a nominal composition CsBSi 2O6 was investigated in air as well as in vacuum. Temperature ranges of negative thermal expansion were found.

AB - The crystal structure of Cs0.82B1.09Si 1.98O6 boropollucite at room temperature was determined by direct methods and refined in the Ia3̄d space group using an anisotropic approximation of atomic thermal displacements (a=13.009 (1) Å, Z=16, Rw=0.027, RF=0.037 for 141 independent observed (F≥4σF) reflections). The occupancy factors have been refined for Cs and tetrahedral positions assuming the oxygen sites being fully occupied. The compound is isostructural to leucite-pollucite high-temperature modification. Thermal behaviour of CsBSi2O6 was investigated by DTA and TG, annealing at different temperatures with following wet chemical analysis and high-temperature X-ray powder diffraction methods. The CsBSi2O6 cubic phase loses mass before melting and decomposes to form a new crystalline phase with close to CsBSi3O 8 stoichiometry in the temperature range of 1303-1353 K. Thermal expansion of two boropollucite samples, which differed in the number of Cs + and/or B3+ ions of a nominal composition CsBSi 2O6 was investigated in air as well as in vacuum. Temperature ranges of negative thermal expansion were found.

KW - Boropollucite

KW - Borosilicate

KW - Crystal structure

KW - Feldspar composition

KW - Phase decomposition

KW - Thermal expansion

UR - http://www.scopus.com/inward/record.url?scp=3242679012&partnerID=8YFLogxK

U2 - 10.1016/j.solidstatesciences.2004.03.015

DO - 10.1016/j.solidstatesciences.2004.03.015

M3 - Article

AN - SCOPUS:3242679012

VL - 6

SP - 629

EP - 637

JO - Solid State Sciences

JF - Solid State Sciences

SN - 1293-2558

IS - 7

ER -

ID: 53951145