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Crystal chemistry of uranyl halides containing mixed (UO 2)(XmOn)5 bipyramids (X = Cl, Br) : Synthesis and crystal structure of Cs2(UO2)(NO3)C 13. / Nazarchuk, Evgeny V.; Siidra, Oleg I.; Krivovichev, Sergey V.

в: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Том 66, № 2, 02.2011, стр. 142-146.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Nazarchuk, EV, Siidra, OI & Krivovichev, SV 2011, 'Crystal chemistry of uranyl halides containing mixed (UO 2)(XmOn)5 bipyramids (X = Cl, Br): Synthesis and crystal structure of Cs2(UO2)(NO3)C 13', Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Том. 66, № 2, стр. 142-146.

APA

Nazarchuk, E. V., Siidra, O. I., & Krivovichev, S. V. (2011). Crystal chemistry of uranyl halides containing mixed (UO 2)(XmOn)5 bipyramids (X = Cl, Br): Synthesis and crystal structure of Cs2(UO2)(NO3)C 13. Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 66(2), 142-146.

Vancouver

Nazarchuk EV, Siidra OI, Krivovichev SV. Crystal chemistry of uranyl halides containing mixed (UO 2)(XmOn)5 bipyramids (X = Cl, Br): Synthesis and crystal structure of Cs2(UO2)(NO3)C 13. Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 2011 Февр.;66(2):142-146.

Author

Nazarchuk, Evgeny V. ; Siidra, Oleg I. ; Krivovichev, Sergey V. / Crystal chemistry of uranyl halides containing mixed (UO 2)(XmOn)5 bipyramids (X = Cl, Br) : Synthesis and crystal structure of Cs2(UO2)(NO3)C 13. в: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 2011 ; Том 66, № 2. стр. 142-146.

BibTeX

@article{d3b6e5ca2985440b9416ed7330c253dc,
title = "Crystal chemistry of uranyl halides containing mixed (UO 2)(XmOn)5 bipyramids (X = Cl, Br): Synthesis and crystal structure of Cs2(UO2)(NO3)C 13",
abstract = "Single crystals of Cs2(UO2)(NO3)Cl 3 were prepared by a hydrothermal method at 205 °C. The crystal structure has been solved by Direct Methods: monoclinic, P21/n, a = 10.3748(13), b = 9.4683(13), c = 12.5535(16) {\AA} β = 110.280(2)°, V = 1156.7(3) {\AA}3, R1 = 0.029. In the structure, strongly bonded linear uranyl cations UO2 2+ are equatorially coordinated by two O and three Cl atoms to form (UO2)Cl3O2 pentagonal bipyramids. Each bipyramid shares its O-O edge with an adjacent (NO3)? anion to form finite clusters with the chemical composition [(UO2)(NO3)Cl 3]2?. The Cs+ cations provide three-dimensional connectivity of the structure by forming Cs-O and Cs-Cl contacts to the uranyl nitrate chloride complexes. Related structures of mixed-ligand uranyl halides are compared.",
keywords = "Chloride, Crystal Chemistry, Crystal Structure, Nitrate, Uranyl",
author = "Nazarchuk, {Evgeny V.} and Siidra, {Oleg I.} and Krivovichev, {Sergey V.}",
year = "2011",
month = feb,
language = "English",
volume = "66",
pages = "142--146",
journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",
issn = "0932-0776",
publisher = "De Gruyter",
number = "2",

}

RIS

TY - JOUR

T1 - Crystal chemistry of uranyl halides containing mixed (UO 2)(XmOn)5 bipyramids (X = Cl, Br)

T2 - Synthesis and crystal structure of Cs2(UO2)(NO3)C 13

AU - Nazarchuk, Evgeny V.

AU - Siidra, Oleg I.

AU - Krivovichev, Sergey V.

PY - 2011/2

Y1 - 2011/2

N2 - Single crystals of Cs2(UO2)(NO3)Cl 3 were prepared by a hydrothermal method at 205 °C. The crystal structure has been solved by Direct Methods: monoclinic, P21/n, a = 10.3748(13), b = 9.4683(13), c = 12.5535(16) Å β = 110.280(2)°, V = 1156.7(3) Å3, R1 = 0.029. In the structure, strongly bonded linear uranyl cations UO2 2+ are equatorially coordinated by two O and three Cl atoms to form (UO2)Cl3O2 pentagonal bipyramids. Each bipyramid shares its O-O edge with an adjacent (NO3)? anion to form finite clusters with the chemical composition [(UO2)(NO3)Cl 3]2?. The Cs+ cations provide three-dimensional connectivity of the structure by forming Cs-O and Cs-Cl contacts to the uranyl nitrate chloride complexes. Related structures of mixed-ligand uranyl halides are compared.

AB - Single crystals of Cs2(UO2)(NO3)Cl 3 were prepared by a hydrothermal method at 205 °C. The crystal structure has been solved by Direct Methods: monoclinic, P21/n, a = 10.3748(13), b = 9.4683(13), c = 12.5535(16) Å β = 110.280(2)°, V = 1156.7(3) Å3, R1 = 0.029. In the structure, strongly bonded linear uranyl cations UO2 2+ are equatorially coordinated by two O and three Cl atoms to form (UO2)Cl3O2 pentagonal bipyramids. Each bipyramid shares its O-O edge with an adjacent (NO3)? anion to form finite clusters with the chemical composition [(UO2)(NO3)Cl 3]2?. The Cs+ cations provide three-dimensional connectivity of the structure by forming Cs-O and Cs-Cl contacts to the uranyl nitrate chloride complexes. Related structures of mixed-ligand uranyl halides are compared.

KW - Chloride

KW - Crystal Chemistry

KW - Crystal Structure

KW - Nitrate

KW - Uranyl

UR - http://www.scopus.com/inward/record.url?scp=79952427453&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:79952427453

VL - 66

SP - 142

EP - 146

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

SN - 0932-0776

IS - 2

ER -

ID: 9145418