Standard

Crystal and molecular structure of adducts of uranyl pivaloyltrifluoroacetonate with hexamethylphosphoramide and of uranyl trifluoroacetylacetonate with trimethyl phosphate. / Sidorenko, G. V.; Grigor'Ev, M. S.; Gurzhiy, V. V.; Krivovichev, S. V.; Suglobov, D. N.

в: Radiochemistry, Том 51, № 6, 12.2009, стр. 567-575.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Sidorenko, GV, Grigor'Ev, MS, Gurzhiy, VV, Krivovichev, SV & Suglobov, DN 2009, 'Crystal and molecular structure of adducts of uranyl pivaloyltrifluoroacetonate with hexamethylphosphoramide and of uranyl trifluoroacetylacetonate with trimethyl phosphate', Radiochemistry, Том. 51, № 6, стр. 567-575. https://doi.org/10.1134/S1066362209060034

APA

Sidorenko, G. V., Grigor'Ev, M. S., Gurzhiy, V. V., Krivovichev, S. V., & Suglobov, D. N. (2009). Crystal and molecular structure of adducts of uranyl pivaloyltrifluoroacetonate with hexamethylphosphoramide and of uranyl trifluoroacetylacetonate with trimethyl phosphate. Radiochemistry, 51(6), 567-575. https://doi.org/10.1134/S1066362209060034

Vancouver

Sidorenko GV, Grigor'Ev MS, Gurzhiy VV, Krivovichev SV, Suglobov DN. Crystal and molecular structure of adducts of uranyl pivaloyltrifluoroacetonate with hexamethylphosphoramide and of uranyl trifluoroacetylacetonate with trimethyl phosphate. Radiochemistry. 2009 Дек.;51(6):567-575. https://doi.org/10.1134/S1066362209060034

Author

Sidorenko, G. V. ; Grigor'Ev, M. S. ; Gurzhiy, V. V. ; Krivovichev, S. V. ; Suglobov, D. N. / Crystal and molecular structure of adducts of uranyl pivaloyltrifluoroacetonate with hexamethylphosphoramide and of uranyl trifluoroacetylacetonate with trimethyl phosphate. в: Radiochemistry. 2009 ; Том 51, № 6. стр. 567-575.

BibTeX

@article{fef9c1adc40840ae8c82c81fe5a4a287,
title = "Crystal and molecular structure of adducts of uranyl pivaloyltrifluoroacetonate with hexamethylphosphoramide and of uranyl trifluoroacetylacetonate with trimethyl phosphate",
abstract = "Crystal and molecular structures of adducts of uranyl pivaloyltrifluoroacetonate with hexamethylphosphoramide [UO2(PTFA)2(HMPA)] (I) and of uranyl trifluoroacetylacetonate with trimethyl phosphate [UO2(TFA)2(TMP)] (II) were determined. Compound I crystallizes in the monoclinic system, space group P21/n; a = 16.9384(3), b = 9.1090(2), c = 20.9844(4) {\AA}, β = 101.5337(10)°, V = 3172.34(11) {\AA}3 (at 100 K); Z = 4. Compound II crystallizes in the rhombic system, space group Pbca; a = 17.8214(4), b = 7.7786(2), c = 30.9176(7) {\AA}, V = 4285.97(18) {\AA}3 (at 100 K); Z = 8. In both cases, the cis isomer in which the neutral ligand is located between the trifluoromethyl groups is realized. Compound I differing from II by the stronger branching of ligand periphery is characterized by stronger structural deformations in the crystal.",
keywords = "β-diketonates, Adducts, Crystal and molecular structure, Single crystal X-ray diffraction, Uranyl",
author = "Sidorenko, {G. V.} and Grigor'Ev, {M. S.} and Gurzhiy, {V. V.} and Krivovichev, {S. V.} and Suglobov, {D. N.}",
year = "2009",
month = dec,
doi = "10.1134/S1066362209060034",
language = "English",
volume = "51",
pages = "567--575",
journal = "Radiochemistry",
issn = "1066-3622",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "6",

}

RIS

TY - JOUR

T1 - Crystal and molecular structure of adducts of uranyl pivaloyltrifluoroacetonate with hexamethylphosphoramide and of uranyl trifluoroacetylacetonate with trimethyl phosphate

AU - Sidorenko, G. V.

AU - Grigor'Ev, M. S.

AU - Gurzhiy, V. V.

AU - Krivovichev, S. V.

AU - Suglobov, D. N.

PY - 2009/12

Y1 - 2009/12

N2 - Crystal and molecular structures of adducts of uranyl pivaloyltrifluoroacetonate with hexamethylphosphoramide [UO2(PTFA)2(HMPA)] (I) and of uranyl trifluoroacetylacetonate with trimethyl phosphate [UO2(TFA)2(TMP)] (II) were determined. Compound I crystallizes in the monoclinic system, space group P21/n; a = 16.9384(3), b = 9.1090(2), c = 20.9844(4) Å, β = 101.5337(10)°, V = 3172.34(11) Å3 (at 100 K); Z = 4. Compound II crystallizes in the rhombic system, space group Pbca; a = 17.8214(4), b = 7.7786(2), c = 30.9176(7) Å, V = 4285.97(18) Å3 (at 100 K); Z = 8. In both cases, the cis isomer in which the neutral ligand is located between the trifluoromethyl groups is realized. Compound I differing from II by the stronger branching of ligand periphery is characterized by stronger structural deformations in the crystal.

AB - Crystal and molecular structures of adducts of uranyl pivaloyltrifluoroacetonate with hexamethylphosphoramide [UO2(PTFA)2(HMPA)] (I) and of uranyl trifluoroacetylacetonate with trimethyl phosphate [UO2(TFA)2(TMP)] (II) were determined. Compound I crystallizes in the monoclinic system, space group P21/n; a = 16.9384(3), b = 9.1090(2), c = 20.9844(4) Å, β = 101.5337(10)°, V = 3172.34(11) Å3 (at 100 K); Z = 4. Compound II crystallizes in the rhombic system, space group Pbca; a = 17.8214(4), b = 7.7786(2), c = 30.9176(7) Å, V = 4285.97(18) Å3 (at 100 K); Z = 8. In both cases, the cis isomer in which the neutral ligand is located between the trifluoromethyl groups is realized. Compound I differing from II by the stronger branching of ligand periphery is characterized by stronger structural deformations in the crystal.

KW - β-diketonates

KW - Adducts

KW - Crystal and molecular structure

KW - Single crystal X-ray diffraction

KW - Uranyl

UR - http://www.scopus.com/inward/record.url?scp=75749095659&partnerID=8YFLogxK

U2 - 10.1134/S1066362209060034

DO - 10.1134/S1066362209060034

M3 - Article

AN - SCOPUS:75749095659

VL - 51

SP - 567

EP - 575

JO - Radiochemistry

JF - Radiochemistry

SN - 1066-3622

IS - 6

ER -

ID: 9152301