Standard

Cross-sensitive rare earth metal ion sensors based on extraction systems. / Legin, A. V.; Babain, V. A.; Kirsanov, D. O.; Mednova, O. V.

в: Sensors and Actuators, B: Chemical, Том 131, № 1, 14.04.2008, стр. 29-36.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Legin, AV, Babain, VA, Kirsanov, DO & Mednova, OV 2008, 'Cross-sensitive rare earth metal ion sensors based on extraction systems', Sensors and Actuators, B: Chemical, Том. 131, № 1, стр. 29-36. https://doi.org/10.1016/j.snb.2007.12.002

APA

Legin, A. V., Babain, V. A., Kirsanov, D. O., & Mednova, O. V. (2008). Cross-sensitive rare earth metal ion sensors based on extraction systems. Sensors and Actuators, B: Chemical, 131(1), 29-36. https://doi.org/10.1016/j.snb.2007.12.002

Vancouver

Legin AV, Babain VA, Kirsanov DO, Mednova OV. Cross-sensitive rare earth metal ion sensors based on extraction systems. Sensors and Actuators, B: Chemical. 2008 Апр. 14;131(1):29-36. https://doi.org/10.1016/j.snb.2007.12.002

Author

Legin, A. V. ; Babain, V. A. ; Kirsanov, D. O. ; Mednova, O. V. / Cross-sensitive rare earth metal ion sensors based on extraction systems. в: Sensors and Actuators, B: Chemical. 2008 ; Том 131, № 1. стр. 29-36.

BibTeX

@article{b3824b47616746b7ae0b7d029939388c,
title = "Cross-sensitive rare earth metal ion sensors based on extraction systems",
abstract = "A variety of new chemical sensors for determination of triple charged rare earth (RE) metal cations from lanthanum(III) to lutetium(III) (lanthanides) has been developed and studied. Well-known extractants-bidentate neutral organophosphorous compounds, such as methylene diphosphine dioxides and carbamoylmethylphosphine oxides and tetraoctyl-3-oxapentanediamide (TODGA) were used as neutral ligands in the polymeric sensor membranes. It was found that addition of certain substances that are called {"}anionic modifiers{"} in sensor terminology (tetra-bistrifluoromethylphenyl-borate (TFPB), chlorinated cobalt dicarbollide (CCD)) often results in increase of sensor sensitivity to lanthanides. Different sensors based on the extractants exhibit remarkable sensitivity to RE metal cations and their selectivity (cross-sensitivity) can be widely governed by changing the composition of the membranes. Chemical sensors based on the extractants show good promise for analysis of RE mixtures in complex solutions containing various other components. The developed sensors can be particularly interesting for the analysis of highly radioactive liquid waste (HLW).",
keywords = "Carbamoylphosphine oxides, Chemical sensors, Chlorinated cobalt dicarbollide, Diphosphine dioxides, Lanthanides, Tetraoctyl-3-oxapentanediamide (TODGA)",
author = "Legin, {A. V.} and Babain, {V. A.} and Kirsanov, {D. O.} and Mednova, {O. V.}",
year = "2008",
month = apr,
day = "14",
doi = "10.1016/j.snb.2007.12.002",
language = "English",
volume = "131",
pages = "29--36",
journal = "Sensors and Actuators, B: Chemical",
issn = "0925-4005",
publisher = "Elsevier",
number = "1",

}

RIS

TY - JOUR

T1 - Cross-sensitive rare earth metal ion sensors based on extraction systems

AU - Legin, A. V.

AU - Babain, V. A.

AU - Kirsanov, D. O.

AU - Mednova, O. V.

PY - 2008/4/14

Y1 - 2008/4/14

N2 - A variety of new chemical sensors for determination of triple charged rare earth (RE) metal cations from lanthanum(III) to lutetium(III) (lanthanides) has been developed and studied. Well-known extractants-bidentate neutral organophosphorous compounds, such as methylene diphosphine dioxides and carbamoylmethylphosphine oxides and tetraoctyl-3-oxapentanediamide (TODGA) were used as neutral ligands in the polymeric sensor membranes. It was found that addition of certain substances that are called "anionic modifiers" in sensor terminology (tetra-bistrifluoromethylphenyl-borate (TFPB), chlorinated cobalt dicarbollide (CCD)) often results in increase of sensor sensitivity to lanthanides. Different sensors based on the extractants exhibit remarkable sensitivity to RE metal cations and their selectivity (cross-sensitivity) can be widely governed by changing the composition of the membranes. Chemical sensors based on the extractants show good promise for analysis of RE mixtures in complex solutions containing various other components. The developed sensors can be particularly interesting for the analysis of highly radioactive liquid waste (HLW).

AB - A variety of new chemical sensors for determination of triple charged rare earth (RE) metal cations from lanthanum(III) to lutetium(III) (lanthanides) has been developed and studied. Well-known extractants-bidentate neutral organophosphorous compounds, such as methylene diphosphine dioxides and carbamoylmethylphosphine oxides and tetraoctyl-3-oxapentanediamide (TODGA) were used as neutral ligands in the polymeric sensor membranes. It was found that addition of certain substances that are called "anionic modifiers" in sensor terminology (tetra-bistrifluoromethylphenyl-borate (TFPB), chlorinated cobalt dicarbollide (CCD)) often results in increase of sensor sensitivity to lanthanides. Different sensors based on the extractants exhibit remarkable sensitivity to RE metal cations and their selectivity (cross-sensitivity) can be widely governed by changing the composition of the membranes. Chemical sensors based on the extractants show good promise for analysis of RE mixtures in complex solutions containing various other components. The developed sensors can be particularly interesting for the analysis of highly radioactive liquid waste (HLW).

KW - Carbamoylphosphine oxides

KW - Chemical sensors

KW - Chlorinated cobalt dicarbollide

KW - Diphosphine dioxides

KW - Lanthanides

KW - Tetraoctyl-3-oxapentanediamide (TODGA)

UR - http://www.scopus.com/inward/record.url?scp=41449097646&partnerID=8YFLogxK

U2 - 10.1016/j.snb.2007.12.002

DO - 10.1016/j.snb.2007.12.002

M3 - Article

AN - SCOPUS:41449097646

VL - 131

SP - 29

EP - 36

JO - Sensors and Actuators, B: Chemical

JF - Sensors and Actuators, B: Chemical

SN - 0925-4005

IS - 1

ER -

ID: 30507214