Complexes of Ir(III) and Pt(II) with cyclometallated 2-phenylbenzothiazole and chelating diethyldithiocarbamate and O-ethyldithiocarbonate ions: Structures and optical and electrochemical properties

Standard

Complexes of Ir(III) and Pt(II) with cyclometallated 2-phenylbenzothiazole and chelating diethyldithiocarbamate and O-ethyldithiocarbonate ions: Structures and optical and electrochemical properties. / Katlenok, E. A.; Zolotarev, A. A.; Ivanov, A. Yu.; Smirnov, S. N.; Baichurin, R. I.; Balashev, K. P.

в: Russian Journal of Coordination Chemistry, Том 42, № 3, 04.05.2016, стр. 178-186.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{0c78927283ec476e95f57be21a551279,

title = "Complexes of Ir(III) and Pt(II) with cyclometallated 2-phenylbenzothiazole and chelating diethyldithiocarbamate and O-ethyldithiocarbonate ions: Structures and optical and electrochemical properties",

abstract = "It is shown by X-ray diffraction analysis, IR spectroscopy, and (1)De, D-13{1H}, and Pt-195 NMR spectroscopy that the Pt(II) and octahedral Ir(III) complexes with metallated 2-phenylbenzothiazole and chelating diethyldithiocarbamate and O-ethyldithiocarbonate ions have the square and cis-C,C structure, respectively. The highest occupied and lowest unoccupied molecular orbitals of the complexes determining their long-wavelength absorption, phosphorescence, and one-electron oxidation and reduction are assigned to those predominantly localized on the mixed p(S)/d(M) and pi* orbitals of the metallated ligand. The cathodic shift of the oxidation voltammogram and the bathochromic phosphorescence shift of the Pt(II) complex with the D-ethyldithiocarbonate ion are attributed to the enhanced donor-acceptor interaction of the donor S atoms of the ligand with Pt(II). The structural data are deposited with the Cambridge Crystallographic Data Centre (CIF files CCDC nos. 1058768 (Ia) and 1058767 (IIb)).",

author = "Katlenok, {E. A.} and Zolotarev, {A. A.} and Ivanov, {A. Yu.} and Smirnov, {S. N.} and Baichurin, {R. I.} and Balashev, {K. P.}",

year = "2016",

month = may,

day = "4",

doi = "10.1134/S1070328416030039",

language = "English",

volume = "42",

pages = "178--186",

journal = "Russian Journal of Coordination Chemistry",

issn = "1070-3284",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "3",

}

RIS

TY - JOUR

T1 - Complexes of Ir(III) and Pt(II) with cyclometallated 2-phenylbenzothiazole and chelating diethyldithiocarbamate and O-ethyldithiocarbonate ions: Structures and optical and electrochemical properties

AU - Katlenok, E. A.

AU - Zolotarev, A. A.

AU - Ivanov, A. Yu.

AU - Smirnov, S. N.

AU - Baichurin, R. I.

AU - Balashev, K. P.

PY - 2016/5/4

Y1 - 2016/5/4

N2 - It is shown by X-ray diffraction analysis, IR spectroscopy, and (1)De, D-13{1H}, and Pt-195 NMR spectroscopy that the Pt(II) and octahedral Ir(III) complexes with metallated 2-phenylbenzothiazole and chelating diethyldithiocarbamate and O-ethyldithiocarbonate ions have the square and cis-C,C structure, respectively. The highest occupied and lowest unoccupied molecular orbitals of the complexes determining their long-wavelength absorption, phosphorescence, and one-electron oxidation and reduction are assigned to those predominantly localized on the mixed p(S)/d(M) and pi* orbitals of the metallated ligand. The cathodic shift of the oxidation voltammogram and the bathochromic phosphorescence shift of the Pt(II) complex with the D-ethyldithiocarbonate ion are attributed to the enhanced donor-acceptor interaction of the donor S atoms of the ligand with Pt(II). The structural data are deposited with the Cambridge Crystallographic Data Centre (CIF files CCDC nos. 1058768 (Ia) and 1058767 (IIb)).

AB - It is shown by X-ray diffraction analysis, IR spectroscopy, and (1)De, D-13{1H}, and Pt-195 NMR spectroscopy that the Pt(II) and octahedral Ir(III) complexes with metallated 2-phenylbenzothiazole and chelating diethyldithiocarbamate and O-ethyldithiocarbonate ions have the square and cis-C,C structure, respectively. The highest occupied and lowest unoccupied molecular orbitals of the complexes determining their long-wavelength absorption, phosphorescence, and one-electron oxidation and reduction are assigned to those predominantly localized on the mixed p(S)/d(M) and pi* orbitals of the metallated ligand. The cathodic shift of the oxidation voltammogram and the bathochromic phosphorescence shift of the Pt(II) complex with the D-ethyldithiocarbonate ion are attributed to the enhanced donor-acceptor interaction of the donor S atoms of the ligand with Pt(II). The structural data are deposited with the Cambridge Crystallographic Data Centre (CIF files CCDC nos. 1058768 (Ia) and 1058767 (IIb)).

U2 - 10.1134/S1070328416030039

DO - 10.1134/S1070328416030039

M3 - Article

VL - 42

SP - 178

EP - 186

JO - Russian Journal of Coordination Chemistry

JF - Russian Journal of Coordination Chemistry

SN - 1070-3284

IS - 3

ER -

ID: 7927530