Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Complexation of Tc(CO)3+•aq with anions of monobasic carboxylic acids in aqueous solutions : A 99Tc NMR study. / Suglobov, D. N.; Miroslavov, A. E.; Sidorenko, G. V.; Gorshkov, N. I.; Lumpov, A. A.
в: Radiochemistry, Том 47, № 1, 01.2005, стр. 50-53.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Complexation of Tc(CO)3+•aq with anions of monobasic carboxylic acids in aqueous solutions
T2 - A 99Tc NMR study
AU - Suglobov, D. N.
AU - Miroslavov, A. E.
AU - Sidorenko, G. V.
AU - Gorshkov, N. I.
AU - Lumpov, A. A.
N1 - Copyright: Copyright 2008 Elsevier B.V., All rights reserved.
PY - 2005/1
Y1 - 2005/1
N2 - Carboxylate anions in aqueous solutions coordinate with the Tc(CO) 3 + ion mainly in the monodentate fashion to form weak 1 : 1, 1 : 2, and 1 : 3 complexes. The stability of the complexes decreases with increasing size of the alkyl radical. In the series of halo-substituted acetates, all the stability constants decrease with a decrease in the basicity of the anion.
AB - Carboxylate anions in aqueous solutions coordinate with the Tc(CO) 3 + ion mainly in the monodentate fashion to form weak 1 : 1, 1 : 2, and 1 : 3 complexes. The stability of the complexes decreases with increasing size of the alkyl radical. In the series of halo-substituted acetates, all the stability constants decrease with a decrease in the basicity of the anion.
UR - http://www.scopus.com/inward/record.url?scp=21644464571&partnerID=8YFLogxK
U2 - 10.1007/s11137-005-0046-1
DO - 10.1007/s11137-005-0046-1
M3 - Article
AN - SCOPUS:21644464571
VL - 47
SP - 50
EP - 53
JO - Radiochemistry
JF - Radiochemistry
SN - 1066-3622
IS - 1
ER -
ID: 76836142