Comb-Like Polyelectrolytes with Quinolinium and Trimethylammonium Cations in Micellar Catalysis

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Comb-Like Polyelectrolytes with Quinolinium and Trimethylammonium Cations in Micellar Catalysis. / Фетин, Петр Александрович; Фетина, Вероника Ивановна; Кадников, Матвей Викторинович ; Лезов, Алексей Андреевич ; Зорин, Иван Михайлович.

в: Polymer Science - Series C, Том 64, № 2, 12.2022, стр. 144-153.

Результаты исследований: Научные публикации в периодических изданиях › Обзорная статья › Рецензирование

BibTeX

@article{0bb805ad429349b2b5de97d1a5142caf,

title = "Comb-Like Polyelectrolytes with Quinolinium and Trimethylammonium Cations in Micellar Catalysis",

abstract = "Abstract—: Homo- and copolymers of poly-11-acryloyloxyundecyltrimethylammonium bromide and poly-11-acryloyloxyundecylquinolinium bromide have been prepared. Molecular parameters and solubilization properties of these polyelectrolytes have been determined. Their catalytic activity in the model reaction of alkaline hydrolysis of p-nitrophenyl butyrate has been investigated. The introduction of the units containing a quinoline moiety has led to consistent growth of the solubilization capacity of the copolymer with respect to a hydrophobic dye, Orange OT. The obtained comb-like polyelectrolytes have been found prone to solubilization over the entire concentration range; they have not possessed critical micelle concentration typical for low-molecular-weight surfactants. Acceleration of the alkaline hydrolysis of the model ester by 2–3 times has been observed in the presence of even low concentration of the comb-like polyelectrolytes. The synthesized polymeric surfactants have not crystallized with the cooling of the solution, in contrast to their monomers and other cationic low-molecular-weight surfactants.",

author = "Фетин, {Петр Александрович} and Фетина, {Вероника Ивановна} and Кадников, {Матвей Викторинович} and Лезов, {Алексей Андреевич} and Зорин, {Иван Михайлович}",

note = "Publisher Copyright: {\textcopyright} 2022, Pleiades Publishing, Ltd.",

year = "2022",

month = dec,

doi = "10.1134/s1811238222700163",

language = "English",

volume = "64",

pages = "144--153",

journal = "Polymer Science - Series C",

issn = "1811-2382",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "2",

}

RIS

TY - JOUR

T1 - Comb-Like Polyelectrolytes with Quinolinium and Trimethylammonium Cations in Micellar Catalysis

AU - Фетин, Петр Александрович

AU - Фетина, Вероника Ивановна

AU - Кадников, Матвей Викторинович

AU - Лезов, Алексей Андреевич

AU - Зорин, Иван Михайлович

PY - 2022/12

Y1 - 2022/12

N2 - Abstract—: Homo- and copolymers of poly-11-acryloyloxyundecyltrimethylammonium bromide and poly-11-acryloyloxyundecylquinolinium bromide have been prepared. Molecular parameters and solubilization properties of these polyelectrolytes have been determined. Their catalytic activity in the model reaction of alkaline hydrolysis of p-nitrophenyl butyrate has been investigated. The introduction of the units containing a quinoline moiety has led to consistent growth of the solubilization capacity of the copolymer with respect to a hydrophobic dye, Orange OT. The obtained comb-like polyelectrolytes have been found prone to solubilization over the entire concentration range; they have not possessed critical micelle concentration typical for low-molecular-weight surfactants. Acceleration of the alkaline hydrolysis of the model ester by 2–3 times has been observed in the presence of even low concentration of the comb-like polyelectrolytes. The synthesized polymeric surfactants have not crystallized with the cooling of the solution, in contrast to their monomers and other cationic low-molecular-weight surfactants.

AB - Abstract—: Homo- and copolymers of poly-11-acryloyloxyundecyltrimethylammonium bromide and poly-11-acryloyloxyundecylquinolinium bromide have been prepared. Molecular parameters and solubilization properties of these polyelectrolytes have been determined. Their catalytic activity in the model reaction of alkaline hydrolysis of p-nitrophenyl butyrate has been investigated. The introduction of the units containing a quinoline moiety has led to consistent growth of the solubilization capacity of the copolymer with respect to a hydrophobic dye, Orange OT. The obtained comb-like polyelectrolytes have been found prone to solubilization over the entire concentration range; they have not possessed critical micelle concentration typical for low-molecular-weight surfactants. Acceleration of the alkaline hydrolysis of the model ester by 2–3 times has been observed in the presence of even low concentration of the comb-like polyelectrolytes. The synthesized polymeric surfactants have not crystallized with the cooling of the solution, in contrast to their monomers and other cationic low-molecular-weight surfactants.

UR - http://www.scopus.com/inward/record.url?scp=85138041881&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/c19d02cb-0866-3403-8cf7-f1eba5bd176d/

U2 - 10.1134/s1811238222700163

DO - 10.1134/s1811238222700163

M3 - Review article

VL - 64

SP - 144

EP - 153

JO - Polymer Science - Series C

JF - Polymer Science - Series C

SN - 1811-2382

IS - 2

ER -

ID: 100661364