Standard

Colored Complexes of Bidentate Lewis Acids R[OB(C6F5)2]2 (R = 1,4-C6H4, 1,4-C6F4) with Pyrazine. / Кудина, Полина Ильинична; Глухович, Екатерина Вячеславовна; Казаков, Игорь Владимирович.

в: Russian Journal of General Chemistry, Том 94, № 11, 17.12.2024, стр. 2915–2919.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

APA

Vancouver

Author

BibTeX

@article{c6f9b30de9c8410bb4b4e67dd70454da,
title = "Colored Complexes of Bidentate Lewis Acids R[OB(C6F5)2]2 (R = 1,4-C6H4, 1,4-C6F4) with Pyrazine",
abstract = "Abstract: Colored complexes of bidentate Lewis acids R[OB(C6F5)2]2 (R = p-C6H4, p-C6F4) with pyrazine have been synthesized. A mass spectrometric study of the obtained complexes was carried out, as a result of which it was established that upon heating, dissociation processes occur with a sequential transition into pyrazine and Lewis acid vapor. Using the method of diffuse reflectance spectroscopy in the visible and ultraviolet regions, the color of the compounds was characterized and a mechanism for its appearance was proposed, which consists in the presence of π–π interactions in the solid phase.",
keywords = "bidentate Lewis acids, donor-acceptor complex, pyrazine, π–π intaraction",
author = "Кудина, {Полина Ильинична} and Глухович, {Екатерина Вячеславовна} and Казаков, {Игорь Владимирович}",
year = "2024",
month = dec,
day = "17",
doi = "10.1134/s1070363224110136",
language = "English",
volume = "94",
pages = "2915–2919",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "11",

}

RIS

TY - JOUR

T1 - Colored Complexes of Bidentate Lewis Acids R[OB(C6F5)2]2 (R = 1,4-C6H4, 1,4-C6F4) with Pyrazine

AU - Кудина, Полина Ильинична

AU - Глухович, Екатерина Вячеславовна

AU - Казаков, Игорь Владимирович

PY - 2024/12/17

Y1 - 2024/12/17

N2 - Abstract: Colored complexes of bidentate Lewis acids R[OB(C6F5)2]2 (R = p-C6H4, p-C6F4) with pyrazine have been synthesized. A mass spectrometric study of the obtained complexes was carried out, as a result of which it was established that upon heating, dissociation processes occur with a sequential transition into pyrazine and Lewis acid vapor. Using the method of diffuse reflectance spectroscopy in the visible and ultraviolet regions, the color of the compounds was characterized and a mechanism for its appearance was proposed, which consists in the presence of π–π interactions in the solid phase.

AB - Abstract: Colored complexes of bidentate Lewis acids R[OB(C6F5)2]2 (R = p-C6H4, p-C6F4) with pyrazine have been synthesized. A mass spectrometric study of the obtained complexes was carried out, as a result of which it was established that upon heating, dissociation processes occur with a sequential transition into pyrazine and Lewis acid vapor. Using the method of diffuse reflectance spectroscopy in the visible and ultraviolet regions, the color of the compounds was characterized and a mechanism for its appearance was proposed, which consists in the presence of π–π interactions in the solid phase.

KW - bidentate Lewis acids

KW - donor-acceptor complex

KW - pyrazine

KW - π–π intaraction

UR - https://link.springer.com/article/10.1134/S1070363224110136?utm_source=rct_congratemailt&utm_medium=email&utm_campaign=nonoa_20241217&utm_content=10.1134%2FS1070363224110136

UR - https://www.mendeley.com/catalogue/2fe1e90c-3ba1-3554-a894-61b9d9c20806/

U2 - 10.1134/s1070363224110136

DO - 10.1134/s1070363224110136

M3 - Article

VL - 94

SP - 2915

EP - 2919

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 11

ER -

ID: 127224172