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CO fluxionality in Rh4(CO)12 and Rh6(CO)16. / Heaton, Brian T.; Jacob, Chacko; Podkorytov, Ivan S.; Tunik, Sergey P.

в: Inorganica Chimica Acta, Том 359, № 11, 01.08.2006, стр. 3557-3564.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Heaton, BT, Jacob, C, Podkorytov, IS & Tunik, SP 2006, 'CO fluxionality in Rh4(CO)12 and Rh6(CO)16', Inorganica Chimica Acta, Том. 359, № 11, стр. 3557-3564. https://doi.org/10.1016/j.ica.2005.12.002

APA

Heaton, B. T., Jacob, C., Podkorytov, I. S., & Tunik, S. P. (2006). CO fluxionality in Rh4(CO)12 and Rh6(CO)16. Inorganica Chimica Acta, 359(11), 3557-3564. https://doi.org/10.1016/j.ica.2005.12.002

Vancouver

Heaton BT, Jacob C, Podkorytov IS, Tunik SP. CO fluxionality in Rh4(CO)12 and Rh6(CO)16. Inorganica Chimica Acta. 2006 Авг. 1;359(11):3557-3564. https://doi.org/10.1016/j.ica.2005.12.002

Author

Heaton, Brian T. ; Jacob, Chacko ; Podkorytov, Ivan S. ; Tunik, Sergey P. / CO fluxionality in Rh4(CO)12 and Rh6(CO)16. в: Inorganica Chimica Acta. 2006 ; Том 359, № 11. стр. 3557-3564.

BibTeX

@article{e66bad983f534bd9bf269345b5654798,
title = "CO fluxionality in Rh4(CO)12 and Rh6(CO)16",
abstract = "Both Rh4(CO)12 and Rh6(CO)16 exhibit CO-fluxionality and modern, variable temperature, NMR methods allow the unambiguous assignment of the three terminal CO resonances and, for Rh4(CO)12, show that the mechanism of CO-fluxionality, which has been controversial for a long time, unambiguously involves the merry-go-round process; Rh6(CO)16, which was previously thought to be static, is also shown to be fluxional, although the rate of CO-exchange is much less than found for substituted derivatives, and possible pathways for this CO-exchange are discussed.",
keywords = "CO fluxionality, Mechanisms, NMR, Rhodium carbonyl clusters",
author = "Heaton, {Brian T.} and Chacko Jacob and Podkorytov, {Ivan S.} and Tunik, {Sergey P.}",
note = "Funding Information: The authors gratefully acknowledge financial support from the Royal Society for an International Joint Awards Grant and an RFBR Grant, 05-03-33266. ",
year = "2006",
month = aug,
day = "1",
doi = "10.1016/j.ica.2005.12.002",
language = "English",
volume = "359",
pages = "3557--3564",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",
number = "11",

}

RIS

TY - JOUR

T1 - CO fluxionality in Rh4(CO)12 and Rh6(CO)16

AU - Heaton, Brian T.

AU - Jacob, Chacko

AU - Podkorytov, Ivan S.

AU - Tunik, Sergey P.

N1 - Funding Information: The authors gratefully acknowledge financial support from the Royal Society for an International Joint Awards Grant and an RFBR Grant, 05-03-33266.

PY - 2006/8/1

Y1 - 2006/8/1

N2 - Both Rh4(CO)12 and Rh6(CO)16 exhibit CO-fluxionality and modern, variable temperature, NMR methods allow the unambiguous assignment of the three terminal CO resonances and, for Rh4(CO)12, show that the mechanism of CO-fluxionality, which has been controversial for a long time, unambiguously involves the merry-go-round process; Rh6(CO)16, which was previously thought to be static, is also shown to be fluxional, although the rate of CO-exchange is much less than found for substituted derivatives, and possible pathways for this CO-exchange are discussed.

AB - Both Rh4(CO)12 and Rh6(CO)16 exhibit CO-fluxionality and modern, variable temperature, NMR methods allow the unambiguous assignment of the three terminal CO resonances and, for Rh4(CO)12, show that the mechanism of CO-fluxionality, which has been controversial for a long time, unambiguously involves the merry-go-round process; Rh6(CO)16, which was previously thought to be static, is also shown to be fluxional, although the rate of CO-exchange is much less than found for substituted derivatives, and possible pathways for this CO-exchange are discussed.

KW - CO fluxionality

KW - Mechanisms

KW - NMR

KW - Rhodium carbonyl clusters

UR - http://www.scopus.com/inward/record.url?scp=33745847168&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2005.12.002

DO - 10.1016/j.ica.2005.12.002

M3 - Article

AN - SCOPUS:33745847168

VL - 359

SP - 3557

EP - 3564

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

IS - 11

ER -

ID: 88616380