TY - JOUR

T1 - Characterization of Greenhouse Gas Emissions from the Territory of the St. Petersburg Agglomeration, Russia, Based on the Results of EMME-2019 and EMME-2020 Mobile Observational Campaigns

AU - Макарова, Мария Владимировна

AU - Фока, Стефани Чарльзовна

AU - Ионов, Дмитрий Викторович

AU - Косцов, Владимир Станиславович

AU - Ивахов, Виктор

AU - Парамонова, Нина

PY - 2025

Y1 - 2025

N2 - Abstract: Saint Petersburg is the second most populous city in the Russian Federation and the fourth in Europe. According to official statistics, ∼5.6 million people permanently live in the city. In order to experimentally estimate greenhouse gas emissions from the territory of the St. Petersburg agglomeration, an original combined approach was developed and implemented during EMME-2019 and ЕММЕ-2020 observational campaigns. The paper summarizes the results of mobile experiments in 2019 and 2020. The period March – early May chosen for the EMME campaigns is shown to be optimal for estimating CO2 emissions. The average anthropogenic additives caused by emissions from the territory of St. Petersburg were assessed at ∼1.07 ppmv for CO2 and ∼6.61 ppbv for CH4. Experimental estimates of specific greenhouse gas fluxes for the territory of the St. Petersburg agglomeration amounted to 72 kt km−2 year−1 CO2 and 198 t km−2 year−1 CH4 for six days of the campaign in 2020; 80 kt km−2 year−1 CO2 and 161 t km−2 year−1 CH4 for 15 days of the campaigns in 2019 and 2020. The CH4/CO2 and CO/CO2 emission ratios for St. Petersburg in March–early May 2020 averaged 6.4 and 5.7 ppbv/ppmv, respectively. Lockdown restrictions due to COVID-19 pandemic affected the structure of emission from the territory of St. Petersburg, namely, a sharp decrease in transport activity significantly decreased CO emissions from motor vehicles.

AB - Abstract: Saint Petersburg is the second most populous city in the Russian Federation and the fourth in Europe. According to official statistics, ∼5.6 million people permanently live in the city. In order to experimentally estimate greenhouse gas emissions from the territory of the St. Petersburg agglomeration, an original combined approach was developed and implemented during EMME-2019 and ЕММЕ-2020 observational campaigns. The paper summarizes the results of mobile experiments in 2019 and 2020. The period March – early May chosen for the EMME campaigns is shown to be optimal for estimating CO2 emissions. The average anthropogenic additives caused by emissions from the territory of St. Petersburg were assessed at ∼1.07 ppmv for CO2 and ∼6.61 ppbv for CH4. Experimental estimates of specific greenhouse gas fluxes for the territory of the St. Petersburg agglomeration amounted to 72 kt km−2 year−1 CO2 and 198 t km−2 year−1 CH4 for six days of the campaign in 2020; 80 kt km−2 year−1 CO2 and 161 t km−2 year−1 CH4 for 15 days of the campaigns in 2019 and 2020. The CH4/CO2 and CO/CO2 emission ratios for St. Petersburg in March–early May 2020 averaged 6.4 and 5.7 ppbv/ppmv, respectively. Lockdown restrictions due to COVID-19 pandemic affected the structure of emission from the territory of St. Petersburg, namely, a sharp decrease in transport activity significantly decreased CO emissions from motor vehicles.

KW - anthropogenic emission

KW - dispersion simulation

KW - greenhouse gas

KW - ground-based remote sensing

KW - megacity

KW - mobile experiment

KW - portable FTIR spectrometer

UR - https://www.mendeley.com/catalogue/9346175f-3182-3000-b0f5-4d2cc3148689/

U2 - 10.1134/s1024856024701045

DO - 10.1134/s1024856024701045

M3 - Article

VL - 37

SP - 786

EP - 797

JO - Atmospheric and Oceanic Optics

JF - Atmospheric and Oceanic Optics

SN - 1024-8560

IS - 6

ER -