We report measurements of the primary charged-particle pseudorapidity density and transverse momentum distributions in p−Pb collisions at √sNN=5.02TeV and investigate their correlation with experimental observables sensitive to the centrality of the collision. Centrality classes are defined by using different event-activity estimators, i.e., charged-particle multiplicities measured in three different pseudorapidity regions as well as the energy measured at beam rapidity (zero degree). The procedures to determine the centrality, quantified by the number of participants (Npart) or the number of nucleon-nucleon binary collisions (Ncoll) are described. We show that, in contrast to Pb-Pb collisions, in p−Pb collisions large multiplicity fluctuations together with the small range of participants available generate a dynamical bias in centrality classes based on particle multiplicity. We propose to use the zero-degree energy, which we expect not to introduce a dynamical bias, as an alternative event-centrality estim