Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Calculations of the thermodynamic properties of glasses and melts in the Cs2O-B2O3-SiO2 system in the framework of the generalized lattice theory of associated solutions. / Plotnikov, E. N.; Stolyarova, V. L.
в: Glass Physics and Chemistry, Том 32, № 2, 03.2006, стр. 181-190.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Calculations of the thermodynamic properties of glasses and melts in the Cs2O-B2O3-SiO2 system in the framework of the generalized lattice theory of associated solutions
AU - Plotnikov, E. N.
AU - Stolyarova, V. L.
N1 - Funding Information: This work was supported by the Russian Foundation for Basic Research, project no. 04-03-32886.
PY - 2006/3
Y1 - 2006/3
N2 - The possibility of calculating the thermodynamic properties of glasses and melts in the Cs2O-B2O3-SiO2 system formed by two glass-former oxides and one modifier oxide with the use of the vacancy variant of the generalized lattice theory of associated solutions is demonstrated. A comparison with the experimental thermodynamic functions determined earlier by high-temperature differential mass spectrometry and electromotive force method shows that the calculations performed within this approach lead to reliable thermodynamic functions. The thermodynamic properties and structural features (the relative numbers of bonds with due regard for the second coordination sphere) of glasses and melts in the Cs2O-B 2O3-SiO2 system are analyzed in terms of the generalized lattice theory of associated solutions.
AB - The possibility of calculating the thermodynamic properties of glasses and melts in the Cs2O-B2O3-SiO2 system formed by two glass-former oxides and one modifier oxide with the use of the vacancy variant of the generalized lattice theory of associated solutions is demonstrated. A comparison with the experimental thermodynamic functions determined earlier by high-temperature differential mass spectrometry and electromotive force method shows that the calculations performed within this approach lead to reliable thermodynamic functions. The thermodynamic properties and structural features (the relative numbers of bonds with due regard for the second coordination sphere) of glasses and melts in the Cs2O-B 2O3-SiO2 system are analyzed in terms of the generalized lattice theory of associated solutions.
UR - http://www.scopus.com/inward/record.url?scp=33646395133&partnerID=8YFLogxK
U2 - 10.1134/S1087659606020106
DO - 10.1134/S1087659606020106
M3 - Article
AN - SCOPUS:33646395133
VL - 32
SP - 181
EP - 190
JO - Glass Physics and Chemistry
JF - Glass Physics and Chemistry
SN - 1087-6596
IS - 2
ER -
ID: 91351652