TY - JOUR

T1 - Calcium-Based Sustainable Chemical Technologies for Total Carbon Recycling

AU - Rodygin, Konstantin S.

AU - Vikenteva, Yulia

AU - Ananikov, Valentine P.

N1 - Publisher Copyright: © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

PY - 2019/4/23

Y1 - 2019/4/23

N2 - Calcium carbide, a stable solid compound composed of two atoms of carbon and one of calcium, has proven its effectiveness in chemical synthesis, due to the safety and convenience of handling the C≡C acetylenic units. The areas of CaC 2 application are very diverse, and the development of calcium-mediated approaches resolves several important challenges. This Review aims to discuss the laboratory chemistry of calcium carbide, and to go beyond its frontiers to organic synthesis, life sciences, materials and construction, carbon dioxide capturing, alloy manufacturing, and agriculture. The recyclability of calcium carbide and the availability of large-scale industrial production facilities, as well as the future possibility of fossil-resource-independent manufacturing, position this compound as a key chemical platform for sustainable development. Easy regeneration and reuse of the carbide highlight calcium-based sustainable chemical technologies as promising instruments for total carbon recycling.

AB - Calcium carbide, a stable solid compound composed of two atoms of carbon and one of calcium, has proven its effectiveness in chemical synthesis, due to the safety and convenience of handling the C≡C acetylenic units. The areas of CaC 2 application are very diverse, and the development of calcium-mediated approaches resolves several important challenges. This Review aims to discuss the laboratory chemistry of calcium carbide, and to go beyond its frontiers to organic synthesis, life sciences, materials and construction, carbon dioxide capturing, alloy manufacturing, and agriculture. The recyclability of calcium carbide and the availability of large-scale industrial production facilities, as well as the future possibility of fossil-resource-independent manufacturing, position this compound as a key chemical platform for sustainable development. Easy regeneration and reuse of the carbide highlight calcium-based sustainable chemical technologies as promising instruments for total carbon recycling.

KW - calcium

KW - carbon

KW - green chemistry

KW - heterogeneous catalysis

KW - sustainable chemistry

KW - ONE-POT SYNTHESIS

KW - SOLID-STATE METATHESIS

KW - CARBIDE-DERIVED CARBONS

KW - LARGE-SCALE SYNTHESIS

KW - RICE HUSK ASH

KW - CO2 CAPTURE PERFORMANCE

KW - GREEN CHEMISTRY

KW - CAC2 PRODUCTION

KW - FLY-ASH

KW - MECHANOCHEMICAL REACTION

UR - http://www.scopus.com/inward/record.url?scp=85063765864&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/calciumbased-sustainable-chemical-technologies-total-carbon-recycling

U2 - 10.1002/cssc.201802412

DO - 10.1002/cssc.201802412

M3 - Review article

VL - 12

SP - 1483

EP - 1516

JO - ChemSusChem

JF - ChemSusChem

SN - 1864-5631

IS - 8

ER -