Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Calcium carbide: Highly potent solid reagent for the construction of heterocycles. / Ледовская, Мария Сергеевна; Воронин, Владимир Владимирович.
в: Tetrahedron, Том 149, 133720, 01.12.2023.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Calcium carbide: Highly potent solid reagent for the construction of heterocycles
AU - Ледовская, Мария Сергеевна
AU - Воронин, Владимир Владимирович
PY - 2023/12/1
Y1 - 2023/12/1
N2 - An analysis of the literature over the past 10 years shows that there is a trend towards simplification of the synthetic procedures, usage of readily available and unexpensive materials, and concern for the safety of the experimental chemist. The use of calcium carbide as a solid acetylene analogue fits this trend perfectly. By replacing gaseous acetylene with calcium carbide, a complex of problems associated with working with gases can be solved at once. Due to this, the chemistry of calcium carbide is rapidly developing, opening up new possibilities of acetylene chemistry. This review highlights recent advances in carbide chemistry demonstrating its advantages in the construction of heterocycles.
AB - An analysis of the literature over the past 10 years shows that there is a trend towards simplification of the synthetic procedures, usage of readily available and unexpensive materials, and concern for the safety of the experimental chemist. The use of calcium carbide as a solid acetylene analogue fits this trend perfectly. By replacing gaseous acetylene with calcium carbide, a complex of problems associated with working with gases can be solved at once. Due to this, the chemistry of calcium carbide is rapidly developing, opening up new possibilities of acetylene chemistry. This review highlights recent advances in carbide chemistry demonstrating its advantages in the construction of heterocycles.
KW - Calcium carbide
KW - Diels-alder reactions
KW - Heterocycles
KW - Sustainable chemistry
KW - 1,3-Dipolar cycloaddition
KW - 1,3-Dipolar cycloaddition
KW - Acetylene
KW - Calcium carbide
KW - Diels-alder reactions
KW - Heterocycles
KW - Sustainable chemistry
UR - https://www.mendeley.com/catalogue/5f353ca3-957e-30de-9edf-a6a1fdba04c4/
U2 - 10.1016/j.tet.2023.133720
DO - 10.1016/j.tet.2023.133720
M3 - Article
VL - 149
JO - Tetrahedron
JF - Tetrahedron
SN - 0040-4020
M1 - 133720
ER -
ID: 113741129