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Calcium carbide: Highly potent solid reagent for the construction of heterocycles. / Ледовская, Мария Сергеевна; Воронин, Владимир Владимирович.

в: Tetrahedron, Том 149, 133720, 01.12.2023.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{0ae286773e664b459bf8beb3d7a0810a,
title = "Calcium carbide: Highly potent solid reagent for the construction of heterocycles",
abstract = "An analysis of the literature over the past 10 years shows that there is a trend towards simplification of the synthetic procedures, usage of readily available and unexpensive materials, and concern for the safety of the experimental chemist. The use of calcium carbide as a solid acetylene analogue fits this trend perfectly. By replacing gaseous acetylene with calcium carbide, a complex of problems associated with working with gases can be solved at once. Due to this, the chemistry of calcium carbide is rapidly developing, opening up new possibilities of acetylene chemistry. This review highlights recent advances in carbide chemistry demonstrating its advantages in the construction of heterocycles.",
keywords = "Calcium carbide, Diels-alder reactions, Heterocycles, Sustainable chemistry, 1,3-Dipolar cycloaddition, 1,3-Dipolar cycloaddition, Acetylene, Calcium carbide, Diels-alder reactions, Heterocycles, Sustainable chemistry",
author = "Ледовская, {Мария Сергеевна} and Воронин, {Владимир Владимирович}",
year = "2023",
month = dec,
day = "1",
doi = "10.1016/j.tet.2023.133720",
language = "English",
volume = "149",
journal = "Tetrahedron",
issn = "0040-4020",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Calcium carbide: Highly potent solid reagent for the construction of heterocycles

AU - Ледовская, Мария Сергеевна

AU - Воронин, Владимир Владимирович

PY - 2023/12/1

Y1 - 2023/12/1

N2 - An analysis of the literature over the past 10 years shows that there is a trend towards simplification of the synthetic procedures, usage of readily available and unexpensive materials, and concern for the safety of the experimental chemist. The use of calcium carbide as a solid acetylene analogue fits this trend perfectly. By replacing gaseous acetylene with calcium carbide, a complex of problems associated with working with gases can be solved at once. Due to this, the chemistry of calcium carbide is rapidly developing, opening up new possibilities of acetylene chemistry. This review highlights recent advances in carbide chemistry demonstrating its advantages in the construction of heterocycles.

AB - An analysis of the literature over the past 10 years shows that there is a trend towards simplification of the synthetic procedures, usage of readily available and unexpensive materials, and concern for the safety of the experimental chemist. The use of calcium carbide as a solid acetylene analogue fits this trend perfectly. By replacing gaseous acetylene with calcium carbide, a complex of problems associated with working with gases can be solved at once. Due to this, the chemistry of calcium carbide is rapidly developing, opening up new possibilities of acetylene chemistry. This review highlights recent advances in carbide chemistry demonstrating its advantages in the construction of heterocycles.

KW - Calcium carbide

KW - Diels-alder reactions

KW - Heterocycles

KW - Sustainable chemistry

KW - 1,3-Dipolar cycloaddition

KW - 1,3-Dipolar cycloaddition

KW - Acetylene

KW - Calcium carbide

KW - Diels-alder reactions

KW - Heterocycles

KW - Sustainable chemistry

UR - https://www.mendeley.com/catalogue/5f353ca3-957e-30de-9edf-a6a1fdba04c4/

U2 - 10.1016/j.tet.2023.133720

DO - 10.1016/j.tet.2023.133720

M3 - Article

VL - 149

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

M1 - 133720

ER -

ID: 113741129