TY - JOUR

T1 - Biomass derived robust Fe4N active sites supported on porous carbons as oxygen reduction reaction catalysts for durable Zn–air batteries

AU - Lu, Xiangyu

AU - Yang, Peixia

AU - Xu, Hao

AU - Xiao, Lihui

AU - Liu, Lilai

AU - Li, Ruopeng

AU - Alekseeva, Elena

AU - Zhang, Jinqiu

AU - Levin, Oleg

AU - An, Maozhong

PY - 2023

Y1 - 2023

N2 - It is necessary to explore affordable, high-performance, and durable catalysts for the oxygen reduction reaction (ORR). Herein, a zinc-assisted pyrolysis-biomass strategy was proposed to prepare robust Fe4N active sites supported on porous carbons (Fe4N@N-C) and achieve a large-scale preparation. Benefiting from the synergistic effect between Fe4N active sites and highly graphitized three-dimensional porous carbon, which possess high intrinsic activity and strong adaptability, the obtained Fe4N@N-C catalyst exhibits a half-wave potential (E1/2) of 0.903 V and remarkable catalytic stability (only a 1 mV negative shift of E1/2 after 5000 cycles) in alkaline media. Theoretical calculations demonstrate that the outstanding activity originates from the synergistic effect of Fe4N sites and graphitic N-doped carbon, which could efficiently reduce the energy barrier in the ORR process. The assembled aqueous and solid-state Zn-air batteries (ZABs) deliver high peak power densities of 182 and 121 mW cm−2. Interestingly, the aqueous ZAB shows a stable cycle for 1033 hours (6198 cycles). This work provides a method for obtaining efficient and durable catalysts as a result of the low-cost and sustainable preparation process of biomass.

AB - It is necessary to explore affordable, high-performance, and durable catalysts for the oxygen reduction reaction (ORR). Herein, a zinc-assisted pyrolysis-biomass strategy was proposed to prepare robust Fe4N active sites supported on porous carbons (Fe4N@N-C) and achieve a large-scale preparation. Benefiting from the synergistic effect between Fe4N active sites and highly graphitized three-dimensional porous carbon, which possess high intrinsic activity and strong adaptability, the obtained Fe4N@N-C catalyst exhibits a half-wave potential (E1/2) of 0.903 V and remarkable catalytic stability (only a 1 mV negative shift of E1/2 after 5000 cycles) in alkaline media. Theoretical calculations demonstrate that the outstanding activity originates from the synergistic effect of Fe4N sites and graphitic N-doped carbon, which could efficiently reduce the energy barrier in the ORR process. The assembled aqueous and solid-state Zn-air batteries (ZABs) deliver high peak power densities of 182 and 121 mW cm−2. Interestingly, the aqueous ZAB shows a stable cycle for 1033 hours (6198 cycles). This work provides a method for obtaining efficient and durable catalysts as a result of the low-cost and sustainable preparation process of biomass.

UR - https://www.mendeley.com/catalogue/f4dfa946-7f0d-3279-bd65-281230e97a0d/

U2 - 10.1039/d2ta08737e

DO - 10.1039/d2ta08737e

M3 - Article

VL - 11

SP - 3725

EP - 3734

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

SN - 2050-7488

IS - 7

ER -