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Bidentate phosphine oxides as ligands to form GaIII shell complexes. [Ga(CH2(P(O)Ph)2)3]3+ : Synthesis, structural and spectroscopic study. / Grachova, E. V.; Linti, G.; Protasova, I. D.; Tunik, S. P.

в: Zeitschrift fur Anorganische und Allgemeine Chemie, Том 635, № 13-14, 01.11.2009, стр. 2294-2296.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Grachova, EV, Linti, G, Protasova, ID & Tunik, SP 2009, 'Bidentate phosphine oxides as ligands to form GaIII shell complexes. [Ga(CH2(P(O)Ph)2)3]3+: Synthesis, structural and spectroscopic study', Zeitschrift fur Anorganische und Allgemeine Chemie, Том. 635, № 13-14, стр. 2294-2296. https://doi.org/10.1002/zaac.200900147

APA

Grachova, E. V., Linti, G., Protasova, I. D., & Tunik, S. P. (2009). Bidentate phosphine oxides as ligands to form GaIII shell complexes. [Ga(CH2(P(O)Ph)2)3]3+: Synthesis, structural and spectroscopic study. Zeitschrift fur Anorganische und Allgemeine Chemie, 635(13-14), 2294-2296. https://doi.org/10.1002/zaac.200900147

Vancouver

Grachova EV, Linti G, Protasova ID, Tunik SP. Bidentate phosphine oxides as ligands to form GaIII shell complexes. [Ga(CH2(P(O)Ph)2)3]3+: Synthesis, structural and spectroscopic study. Zeitschrift fur Anorganische und Allgemeine Chemie. 2009 Нояб. 1;635(13-14):2294-2296. https://doi.org/10.1002/zaac.200900147

Author

Grachova, E. V. ; Linti, G. ; Protasova, I. D. ; Tunik, S. P. / Bidentate phosphine oxides as ligands to form GaIII shell complexes. [Ga(CH2(P(O)Ph)2)3]3+ : Synthesis, structural and spectroscopic study. в: Zeitschrift fur Anorganische und Allgemeine Chemie. 2009 ; Том 635, № 13-14. стр. 2294-2296.

BibTeX

@article{a6d1bf93d6ee4dc388d9f3e2ceca8a7d,
title = "Bidentate phosphine oxides as ligands to form GaIII shell complexes. [Ga(CH2(P(O)Ph)2)3]3+: Synthesis, structural and spectroscopic study",
abstract = "The tri-cationic shell gallium complex [Ga(CH2(P(O)Ph) 2)3]3+ containing three neutral diphosphate oxide ligands has been synthesized and structurally characterized by using X-ray crystallography, mass spectrometry, and 1H, 13C, 31P, and 71Ga NMR spectroscopy. The ligands form three equivalent six-membered chelate cycles to give an idealized octahedral environment around the Ga3+ ion. This compound is the first example of a mononuclear homoleptic octahedral structure formed by neutral phosphine oxide ligands in the chemistry of the 13 group elements in the +3 oxidation state.",
keywords = "Chelates, Gallium, O ligands, Shell complex, X-ray diffraction",
author = "Grachova, {E. V.} and G. Linti and Protasova, {I. D.} and Tunik, {S. P.}",
year = "2009",
month = nov,
day = "1",
doi = "10.1002/zaac.200900147",
language = "English",
volume = "635",
pages = "2294--2296",
journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",
issn = "0044-2313",
publisher = "Wiley-Blackwell",
number = "13-14",

}

RIS

TY - JOUR

T1 - Bidentate phosphine oxides as ligands to form GaIII shell complexes. [Ga(CH2(P(O)Ph)2)3]3+

T2 - Synthesis, structural and spectroscopic study

AU - Grachova, E. V.

AU - Linti, G.

AU - Protasova, I. D.

AU - Tunik, S. P.

PY - 2009/11/1

Y1 - 2009/11/1

N2 - The tri-cationic shell gallium complex [Ga(CH2(P(O)Ph) 2)3]3+ containing three neutral diphosphate oxide ligands has been synthesized and structurally characterized by using X-ray crystallography, mass spectrometry, and 1H, 13C, 31P, and 71Ga NMR spectroscopy. The ligands form three equivalent six-membered chelate cycles to give an idealized octahedral environment around the Ga3+ ion. This compound is the first example of a mononuclear homoleptic octahedral structure formed by neutral phosphine oxide ligands in the chemistry of the 13 group elements in the +3 oxidation state.

AB - The tri-cationic shell gallium complex [Ga(CH2(P(O)Ph) 2)3]3+ containing three neutral diphosphate oxide ligands has been synthesized and structurally characterized by using X-ray crystallography, mass spectrometry, and 1H, 13C, 31P, and 71Ga NMR spectroscopy. The ligands form three equivalent six-membered chelate cycles to give an idealized octahedral environment around the Ga3+ ion. This compound is the first example of a mononuclear homoleptic octahedral structure formed by neutral phosphine oxide ligands in the chemistry of the 13 group elements in the +3 oxidation state.

KW - Chelates

KW - Gallium

KW - O ligands

KW - Shell complex

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=70449597321&partnerID=8YFLogxK

U2 - 10.1002/zaac.200900147

DO - 10.1002/zaac.200900147

M3 - Article

AN - SCOPUS:70449597321

VL - 635

SP - 2294

EP - 2296

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

SN - 0044-2313

IS - 13-14

ER -

ID: 36016243