Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Azomethine ylides derived from dichlorocarbene and O-acylsalicylaldehyde anils in the synthesis of 2,5-epoxy-2,3,4,5-tetrahydro-1,4-benzoxazepin-2-ones and 2-aminoethanols. / Voznyi, I. V.; Novikov, M. S.; Khlebnikov, A. F.; Kostikov, R. R.
в: Russian Chemical Bulletin, Том 53, № 5, 05.2004, стр. 1087-1091.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Azomethine ylides derived from dichlorocarbene and O-acylsalicylaldehyde anils in the synthesis of 2,5-epoxy-2,3,4,5-tetrahydro-1,4-benzoxazepin-2-ones and 2-aminoethanols
AU - Voznyi, I. V.
AU - Novikov, M. S.
AU - Khlebnikov, A. F.
AU - Kostikov, R. R.
N1 - Funding Information: This study was financially supported by the Russian Foundation for Basic Research (Project No. 02 03 32735a) and the Ministry of Education of the Russian Federation (Project No. E02 5.0 30).
PY - 2004/5
Y1 - 2004/5
N2 - Iminiodichloromethanides generated by the reaction of O-acylsalicylaldehyde anils with dichlorocarbene undergo regioselective intramolecular 1,3-dipolar cycloaddition to the ester carbonyl group to give 2,5-epoxy-2,3,4,5-tetrahydro- 1,4-benzoxazepin-2-ones. These compounds are expedient precursors for the synthesis of N-(2-hydroxybenzyl)ethanolamines.
AB - Iminiodichloromethanides generated by the reaction of O-acylsalicylaldehyde anils with dichlorocarbene undergo regioselective intramolecular 1,3-dipolar cycloaddition to the ester carbonyl group to give 2,5-epoxy-2,3,4,5-tetrahydro- 1,4-benzoxazepin-2-ones. These compounds are expedient precursors for the synthesis of N-(2-hydroxybenzyl)ethanolamines.
KW - aminoethanols
KW - azomethine ylides
KW - cycloaddition
KW - dihalocarbenes
UR - http://www.scopus.com/inward/record.url?scp=4544324176&partnerID=8YFLogxK
U2 - 10.1023/B:RUCB.0000041304.68814.83
DO - 10.1023/B:RUCB.0000041304.68814.83
M3 - Article
AN - SCOPUS:4544324176
VL - 53
SP - 1087
EP - 1091
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 5
ER -
ID: 99352466