Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Atoms state and interatomic interactions in perovskite-like oxides: XXXII. Formation of paramagnetic clusters in the La1-0.33x Ca 0.33x Fe x Al1-x O3 and La 1-0.33x Sr0.33x Fe x Al1-x O 3 solid solutions. / Chezhina, N.V.; Fedorova, A.V.; Musatov, S.M.
в: Russian Journal of General Chemistry, № 9, 2013, стр. 1645-1648.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Atoms state and interatomic interactions in perovskite-like oxides: XXXII. Formation of paramagnetic clusters in the La1-0.33x Ca 0.33x Fe x Al1-x O3 and La 1-0.33x Sr0.33x Fe x Al1-x O 3 solid solutions
AU - Chezhina, N.V.
AU - Fedorova, A.V.
AU - Musatov, S.M.
PY - 2013
Y1 - 2013
N2 - Calcium- and strontium-containing lanthanum orthoferrites have been studied using magnetic dilution method. It has been shown that the iron-atom clusters with competing ferro- and antiferromagnetic exchange interactions can exist. By using Mossbauer spectroscopy, Fe(IV) atoms have been found in the La 1-0.33x Ca0.33x FexAl1-x O 3 solid solutions and Fe(III) atoms in two different surroundings have been found in the La1-0.33x Sr0.33x Fe x Al1-x O3 solid solutions. The compositions of paramagnetic clusters stable at the infinite dilution have been proposed basing of the magnetic susceptibility and Mossbauer spectroscopy data. © 2013 Pleiades Publishing, Ltd.
AB - Calcium- and strontium-containing lanthanum orthoferrites have been studied using magnetic dilution method. It has been shown that the iron-atom clusters with competing ferro- and antiferromagnetic exchange interactions can exist. By using Mossbauer spectroscopy, Fe(IV) atoms have been found in the La 1-0.33x Ca0.33x FexAl1-x O 3 solid solutions and Fe(III) atoms in two different surroundings have been found in the La1-0.33x Sr0.33x Fe x Al1-x O3 solid solutions. The compositions of paramagnetic clusters stable at the infinite dilution have been proposed basing of the magnetic susceptibility and Mossbauer spectroscopy data. © 2013 Pleiades Publishing, Ltd.
U2 - 10.1134/S107036321309003X
DO - 10.1134/S107036321309003X
M3 - Article
SP - 1645
EP - 1648
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 9
ER -
ID: 7522446