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Application of the Matrix Method for Calculating Internal Equilibrium Constants and Complex Formation Microconstants. / Kudrev, A. G.
в: Russian Journal of General Chemistry, Том 89, № 6, 2019, стр. 1115-1128.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Application of the Matrix Method for Calculating Internal Equilibrium Constants and Complex Formation Microconstants
AU - Kudrev, A. G.
N1 - Kudrev, A.G. Russ J Gen Chem (2019) 89: 1115. https://doi.org/10.1134/S1070363219060057
PY - 2019
Y1 - 2019
N2 - This review is devoted to the matrix method of simulating complex formation in solution. The applicability of the method to the interpretation of spectrometric and calorimetric data for systems containing simultaneously a large number of complex forms is shown. The works where this method was used to calculate the internal equilibrium constants and cis/trans isomerization constants were analyzed. Using the matrix simulation method, the cooperativity of ammonia binding by Mg2+, Ca2+, Zn2+, Cd2+, and Ni2+ ions in aqueous solution was demonstrated. For halide complexes of Pt(II), Pd(II) and Au(III) with a square-planar structure, the difference between the mutual influence of ligands in the cis and trans isomers is shown. The question of verifying the hypothesis about the geometry of the coordination polyhedron of Cu2+ compounds formed in the processes of equilibrium stepwise complex formation in mixed solvents is considered.
AB - This review is devoted to the matrix method of simulating complex formation in solution. The applicability of the method to the interpretation of spectrometric and calorimetric data for systems containing simultaneously a large number of complex forms is shown. The works where this method was used to calculate the internal equilibrium constants and cis/trans isomerization constants were analyzed. Using the matrix simulation method, the cooperativity of ammonia binding by Mg2+, Ca2+, Zn2+, Cd2+, and Ni2+ ions in aqueous solution was demonstrated. For halide complexes of Pt(II), Pd(II) and Au(III) with a square-planar structure, the difference between the mutual influence of ligands in the cis and trans isomers is shown. The question of verifying the hypothesis about the geometry of the coordination polyhedron of Cu2+ compounds formed in the processes of equilibrium stepwise complex formation in mixed solvents is considered.
KW - intrinsic constants
KW - matrix method
KW - matrix model of complex formation
KW - X-RAY-DIFFRACTION
KW - ION MEDIUM
KW - PARAMETERS
KW - STEPWISE DISSOCIATION
KW - AQUEOUS SOLUTION
KW - LIGANDS
KW - COOPERATIVITY
KW - G-QUADRUPLEX DNA
KW - BINDING
KW - COPPER(II) CHLORO COMPLEXES
UR - http://www.scopus.com/inward/record.url?scp=85068653953&partnerID=8YFLogxK
UR - http://www.mendeley.com/research/application-matrix-method-calculating-internal-equilibrium-constants-complex-formation-microconstant
U2 - 10.1134/S1070363219060057
DO - 10.1134/S1070363219060057
M3 - Article
AN - SCOPUS:85068653953
VL - 89
SP - 1115
EP - 1128
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 6
ER -
ID: 47621875