Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Application of copper(I) halides to modifying reactivity of Polyhalomethanes and arenesulfonyl chlorides in free-radical addition. "cross-halogenation" reaction. / Dneprovskii, A. S.; Kasatochkin, A. N.; Boyarskii, V. P.; Ermoshkin, A. A.
в: Russian Journal of Organic Chemistry, Том 42, № 8, 08.2006, стр. 1120-1130.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Application of copper(I) halides to modifying reactivity of Polyhalomethanes and arenesulfonyl chlorides in free-radical addition. "cross-halogenation" reaction
AU - Dneprovskii, A. S.
AU - Kasatochkin, A. N.
AU - Boyarskii, V. P.
AU - Ermoshkin, A. A.
PY - 2006/8
Y1 - 2006/8
N2 - In the free-radical addition of a number of organohalogen reagents to cyclic alkenes and dienes in the presence of copper(I) halides the composition of the reaction products is governed by the stage of a fast halogen transfer from the copper derivative to the alkyl radical. Under these conditions in contrast to the free-radical addition reactions initiated by UV light or peroxide initiators the intramolecular rearrangements are suppressed, the stereoselectivity of the reaction changes, and also some adducts contain halogen atoms different from those present in the organohalogen reagent employed.
AB - In the free-radical addition of a number of organohalogen reagents to cyclic alkenes and dienes in the presence of copper(I) halides the composition of the reaction products is governed by the stage of a fast halogen transfer from the copper derivative to the alkyl radical. Under these conditions in contrast to the free-radical addition reactions initiated by UV light or peroxide initiators the intramolecular rearrangements are suppressed, the stereoselectivity of the reaction changes, and also some adducts contain halogen atoms different from those present in the organohalogen reagent employed.
UR - http://www.scopus.com/inward/record.url?scp=33748939446&partnerID=8YFLogxK
U2 - 10.1134/S1070428006080033
DO - 10.1134/S1070428006080033
M3 - Article
AN - SCOPUS:33748939446
VL - 42
SP - 1120
EP - 1130
JO - Russian Journal of Organic Chemistry
JF - Russian Journal of Organic Chemistry
SN - 1070-4280
IS - 8
ER -
ID: 87471169