DOI

  • Yu G. Mourzina
  • Yu E. Ermolenko
  • T. Yoshinobu
  • Yu Vlasov
  • H. Iwasaki
  • M. J. Schöning

The technology of fabrication of anion-selective light-addressable potentiometric sensors (LAPS) by using a solid-state microelectronic device integrated with an ion-recognition membrane has been elaborated. The nitrate sensor with ion-exchange membrane exhibits a linear response interval of 3 × 10-5 to 1 × 10-1 mol/l NO3- with an ionic sensitivity of 58 ± 2mV/pNO3. The detection limit was found to be 1 × 10-5 mol/l of nitrate ions and the working pH interval of the sensor is 2.0-11 for 10-2 mol/l NO3-. The sensor has a high selectivity for nitrate over chloride, sulphate, hydrogen phosphate and acetate ions with selectivity coefficients, KNO3/X, of 7 × 10-3, 1 × 10-3, 2 × 10-4 and 5 × 10-3, respectively, and a response time of about 1 min. The SO4-LAPS with polymeric membrane containing neutral sulphate ionophore demonstrates a sensitivity of 26 ± 1 mV/pSO4 in a concentration range of 3 × 10-6 to 1 × 10-2mol/l with a reasonable selectivity over chloride, hydrogen carbonate and hydrogen phosphate ions. Selectivity coefficients, KSO4/X, were found to be 0.6, 0.15 and 0.03, respectively.

Язык оригиналаанглийский
Страницы (с-по)32-38
Число страниц7
ЖурналSensors and Actuators, B: Chemical
Том91
Номер выпуска1-3
DOI
СостояниеОпубликовано - 1 июн 2003
Событие9th International Meeting on Chemical Sensors - BOSTON, Марокко
Продолжительность: 7 июл 200210 июл 2002

    Предметные области Scopus

  • Электроника, оптика и магнитные материалы
  • Контрольно-измерительные инструменты
  • Физика конденсатов
  • Поверхности, слои и пленки
  • Металлы и сплавы
  • Электротехника и электроника
  • Химия материалов

ID: 61610352