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Al(OCAr F 3)3-a thermally stable Lewis superacid. / Kögel, Julius F.; Timoshkin, Alexey Y.; Schröder, Artem; Lork, Enno; Beckmann, Jens.

в: Chemical Science, Том 9, № 43, 21.11.2018, стр. 8178-8183.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Kögel, JF, Timoshkin, AY, Schröder, A, Lork, E & Beckmann, J 2018, 'Al(OCAr F 3)3-a thermally stable Lewis superacid', Chemical Science, Том. 9, № 43, стр. 8178-8183. https://doi.org/10.1039/c8sc02981d

APA

Kögel, J. F., Timoshkin, A. Y., Schröder, A., Lork, E., & Beckmann, J. (2018). Al(OCAr F 3)3-a thermally stable Lewis superacid. Chemical Science, 9(43), 8178-8183. https://doi.org/10.1039/c8sc02981d

Vancouver

Kögel JF, Timoshkin AY, Schröder A, Lork E, Beckmann J. Al(OCAr F 3)3-a thermally stable Lewis superacid. Chemical Science. 2018 Нояб. 21;9(43):8178-8183. https://doi.org/10.1039/c8sc02981d

Author

Kögel, Julius F. ; Timoshkin, Alexey Y. ; Schröder, Artem ; Lork, Enno ; Beckmann, Jens. / Al(OCAr F 3)3-a thermally stable Lewis superacid. в: Chemical Science. 2018 ; Том 9, № 43. стр. 8178-8183.

BibTeX

@article{2bb7ea32807e4c5897c681df2bbd36e1,
title = "Al(OCAr F 3)3-a thermally stable Lewis superacid",
abstract = "The adduct free Lewis superacid Al(OCArF3)3 was obtained by the reaction of ArF3COH with AlEt3 and fully characterized (ArF = C6F5). It comprises a high thermal stability up to 180 °C and a distinct reactivity towards Lewis bases, as exemplified by the isolation of the neutral adducts Al(OCArF3)·D (D = MeCN, THF, Et2O, pyridine, OPEt3), the fluoride complexes [Q][FAl(OCArF)3] (Q+ = Cs+, Ag+, Tl+, [S(NMe2)3]+, [Ph3C]+, Li+, [NBu4]+, [FeCp2]+) and the chloride complex [Ph3C][ClAl(OCArF)3].",
keywords = "WEAKLY COORDINATING ANIONS, ION AFFINITIES, ACID CATALYSIS, CHEMISTRY, FLUORIDE, CATIONS, COMPLEXES, CRYSTAL, PAIRS",
author = "K{\"o}gel, {Julius F.} and Timoshkin, {Alexey Y.} and Artem Schr{\"o}der and Enno Lork and Jens Beckmann",
year = "2018",
month = nov,
day = "21",
doi = "10.1039/c8sc02981d",
language = "English",
volume = "9",
pages = "8178--8183",
journal = "Chemical Science",
issn = "2041-6520",
publisher = "Royal Society of Chemistry",
number = "43",

}

RIS

TY - JOUR

T1 - Al(OCAr F 3)3-a thermally stable Lewis superacid

AU - Kögel, Julius F.

AU - Timoshkin, Alexey Y.

AU - Schröder, Artem

AU - Lork, Enno

AU - Beckmann, Jens

PY - 2018/11/21

Y1 - 2018/11/21

N2 - The adduct free Lewis superacid Al(OCArF3)3 was obtained by the reaction of ArF3COH with AlEt3 and fully characterized (ArF = C6F5). It comprises a high thermal stability up to 180 °C and a distinct reactivity towards Lewis bases, as exemplified by the isolation of the neutral adducts Al(OCArF3)·D (D = MeCN, THF, Et2O, pyridine, OPEt3), the fluoride complexes [Q][FAl(OCArF)3] (Q+ = Cs+, Ag+, Tl+, [S(NMe2)3]+, [Ph3C]+, Li+, [NBu4]+, [FeCp2]+) and the chloride complex [Ph3C][ClAl(OCArF)3].

AB - The adduct free Lewis superacid Al(OCArF3)3 was obtained by the reaction of ArF3COH with AlEt3 and fully characterized (ArF = C6F5). It comprises a high thermal stability up to 180 °C and a distinct reactivity towards Lewis bases, as exemplified by the isolation of the neutral adducts Al(OCArF3)·D (D = MeCN, THF, Et2O, pyridine, OPEt3), the fluoride complexes [Q][FAl(OCArF)3] (Q+ = Cs+, Ag+, Tl+, [S(NMe2)3]+, [Ph3C]+, Li+, [NBu4]+, [FeCp2]+) and the chloride complex [Ph3C][ClAl(OCArF)3].

KW - WEAKLY COORDINATING ANIONS

KW - ION AFFINITIES

KW - ACID CATALYSIS

KW - CHEMISTRY

KW - FLUORIDE

KW - CATIONS

KW - COMPLEXES

KW - CRYSTAL

KW - PAIRS

UR - http://www.scopus.com/inward/record.url?scp=85056301534&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/alocar-f-33a-thermally-stable-lewis-superacid

U2 - 10.1039/c8sc02981d

DO - 10.1039/c8sc02981d

M3 - Article

AN - SCOPUS:85056301534

VL - 9

SP - 8178

EP - 8183

JO - Chemical Science

JF - Chemical Science

SN - 2041-6520

IS - 43

ER -

ID: 35950144