Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Ag/Na Ion Exchange in Fluorophosphate Glasses and Formation of Ag Nanoparticles in the Bulk and on the Surface of the Glass. / Kolobkova, Elena; Kuznetsova, Maria Sergeevna; Nikonorov, Nikolai.
в: ACS Applied Nano Materials, Том 2, № 11, 22.11.2019, стр. 6928-6938.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Ag/Na Ion Exchange in Fluorophosphate Glasses and Formation of Ag Nanoparticles in the Bulk and on the Surface of the Glass
AU - Kolobkova, Elena
AU - Kuznetsova, Maria Sergeevna
AU - Nikonorov, Nikolai
PY - 2019/11/22
Y1 - 2019/11/22
N2 - Nanoscale silver clusters and metal Ag nanoparticles embedded in fluorophosphate glass were produced by Na/Ag ion exchange and subsequent heat treatment. The studied ion exchange was found to provide the reduction of Ag+ ions to Ag0 and formation of the small Ag2-4 clusters featuring intensive luminescence. Treatment at the temperatures 320-410 °C resulted in the appearance of two surface plasmon resonance (SPR) bands corresponding to large clusters Agn (n = 11-70) with blue-shifted plasmonic band and metal Ag nanoparticles. Two different SERS substrates were obtained by an out-diffusion technique. A silver nanoisland structure was grown after heat treatment in the oxygen atmosphere. The nanoporous Ag films with a rough surface were grown in hydrogen atmosphere. The nanoporous Ag film was used as the substrate for SERS. It was found that sensitivity of the nanoporous Ag film grown on the fluorophosphate glass is close to results of SERS obtained on island structures grown on silicate glasses.
AB - Nanoscale silver clusters and metal Ag nanoparticles embedded in fluorophosphate glass were produced by Na/Ag ion exchange and subsequent heat treatment. The studied ion exchange was found to provide the reduction of Ag+ ions to Ag0 and formation of the small Ag2-4 clusters featuring intensive luminescence. Treatment at the temperatures 320-410 °C resulted in the appearance of two surface plasmon resonance (SPR) bands corresponding to large clusters Agn (n = 11-70) with blue-shifted plasmonic band and metal Ag nanoparticles. Two different SERS substrates were obtained by an out-diffusion technique. A silver nanoisland structure was grown after heat treatment in the oxygen atmosphere. The nanoporous Ag films with a rough surface were grown in hydrogen atmosphere. The nanoporous Ag film was used as the substrate for SERS. It was found that sensitivity of the nanoporous Ag film grown on the fluorophosphate glass is close to results of SERS obtained on island structures grown on silicate glasses.
KW - Ag metal nanoparticles
KW - Ag/Na ion exchange
KW - island structure, porous Ag films
KW - surface enhanced Raman spectroscopy
KW - surface plasmon resonance
UR - http://www.scopus.com/inward/record.url?scp=85074691523&partnerID=8YFLogxK
U2 - 10.1021/acsanm.9b01419
DO - 10.1021/acsanm.9b01419
M3 - Article
AN - SCOPUS:85074691523
VL - 2
SP - 6928
EP - 6938
JO - ACS Applied Nano Materials
JF - ACS Applied Nano Materials
SN - 2574-0970
IS - 11
ER -
ID: 49982439