Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Adsorption-induced gap states of h-BN on metal surfaces. / Preobrajenski, A. B.; Krasnikov, S. A.; Vinogradov, A. S.; Ng, May Ling; Käämbre, T.; Cafolla, A. A.; Mårtensson, N.
в: Physical Review B - Condensed Matter and Materials Physics, Том 77, № 8, 085421, 19.02.2008.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Adsorption-induced gap states of h-BN on metal surfaces
AU - Preobrajenski, A. B.
AU - Krasnikov, S. A.
AU - Vinogradov, A. S.
AU - Ng, May Ling
AU - Käämbre, T.
AU - Cafolla, A. A.
AU - Mårtensson, N.
N1 - Copyright: Copyright 2008 Elsevier B.V., All rights reserved.
PY - 2008/2/19
Y1 - 2008/2/19
N2 - The formation of hexagonal boron nitride (h-BN) monolayers on Ni(111), Rh(111), and Pt(111) has been studied by a combination of x-ray emission, angle-resolved valence band photoemission, and x-ray absorption in search for interface-induced gap states of h-BN. A significant density of both occupied and unoccupied gap states with N 2p and B 2p characters is observed for h-BN Ni (111), somewhat less for h-BN Rh (111) and still less for h-BN Pt (111). X-ray emission shows that the h-BN monolayer is chemisorbed strongly on Ni(111) and very weakly on Pt(111). We associate the gap states of h-BN adsorbed on the transition metal surfaces with the orbital mixing and electron sharing at the interface because their density increases with the growing strength of chemisorption.
AB - The formation of hexagonal boron nitride (h-BN) monolayers on Ni(111), Rh(111), and Pt(111) has been studied by a combination of x-ray emission, angle-resolved valence band photoemission, and x-ray absorption in search for interface-induced gap states of h-BN. A significant density of both occupied and unoccupied gap states with N 2p and B 2p characters is observed for h-BN Ni (111), somewhat less for h-BN Rh (111) and still less for h-BN Pt (111). X-ray emission shows that the h-BN monolayer is chemisorbed strongly on Ni(111) and very weakly on Pt(111). We associate the gap states of h-BN adsorbed on the transition metal surfaces with the orbital mixing and electron sharing at the interface because their density increases with the growing strength of chemisorption.
UR - http://www.scopus.com/inward/record.url?scp=40849094399&partnerID=8YFLogxK
U2 - 10.1103/PhysRevB.77.085421
DO - 10.1103/PhysRevB.77.085421
M3 - Article
AN - SCOPUS:40849094399
VL - 77
JO - Physical Review B-Condensed Matter
JF - Physical Review B-Condensed Matter
SN - 1098-0121
IS - 8
M1 - 085421
ER -
ID: 76050407