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Addition of bromotrichloromethane and tetrachloromethane to cis-cyclooctene, cyclohexene, and norbornadiene in the presence of palladium(II) complexes. / Dneprovskii, A. S.; Ermoshkin, A. A.; Kasatochkin, A. N.; Boyarskii, V. P.

в: Russian Journal of Organic Chemistry, Том 39, № 7, 07.2003, стр. 933-946.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Dneprovskii, A. S. ; Ermoshkin, A. A. ; Kasatochkin, A. N. ; Boyarskii, V. P. / Addition of bromotrichloromethane and tetrachloromethane to cis-cyclooctene, cyclohexene, and norbornadiene in the presence of palladium(II) complexes. в: Russian Journal of Organic Chemistry. 2003 ; Том 39, № 7. стр. 933-946.

BibTeX

@article{446d556015154edb84ab96a8496e2f43,
title = "Addition of bromotrichloromethane and tetrachloromethane to cis-cyclooctene, cyclohexene, and norbornadiene in the presence of palladium(II) complexes",
abstract = "Addition of bromotrichloromethane and tetrachloromethane to alkenes in the presence of palladium(II) complexes begins with single-electron transfer from the palladium atom to polyhalomethane molecule, followed by fragmentation of the radical anion thus formed and generation of trichloromethyl radical. Halogen transfer to a carbon-centered radical arising from addition of trichloromethyl radical at the double bond occurs both from the polyhalomethane molecule and from halide palladium complex.",
author = "Dneprovskii, {A. S.} and Ermoshkin, {A. A.} and Kasatochkin, {A. N.} and Boyarskii, {V. P.}",
note = "Funding Information: This study was financially supported by the Russian Foundation for Basic Research (project no. 01-03-32 330a) and by the Universities of Russia Foundation (project no. UR.05.01.011).",
year = "2003",
month = jul,
doi = "10.1023/B:RUJO.0000003181.02370.cf",
language = "English",
volume = "39",
pages = "933--946",
journal = "Russian Journal of Organic Chemistry",
issn = "1070-4280",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "7",

}

RIS

TY - JOUR

T1 - Addition of bromotrichloromethane and tetrachloromethane to cis-cyclooctene, cyclohexene, and norbornadiene in the presence of palladium(II) complexes

AU - Dneprovskii, A. S.

AU - Ermoshkin, A. A.

AU - Kasatochkin, A. N.

AU - Boyarskii, V. P.

N1 - Funding Information: This study was financially supported by the Russian Foundation for Basic Research (project no. 01-03-32 330a) and by the Universities of Russia Foundation (project no. UR.05.01.011).

PY - 2003/7

Y1 - 2003/7

N2 - Addition of bromotrichloromethane and tetrachloromethane to alkenes in the presence of palladium(II) complexes begins with single-electron transfer from the palladium atom to polyhalomethane molecule, followed by fragmentation of the radical anion thus formed and generation of trichloromethyl radical. Halogen transfer to a carbon-centered radical arising from addition of trichloromethyl radical at the double bond occurs both from the polyhalomethane molecule and from halide palladium complex.

AB - Addition of bromotrichloromethane and tetrachloromethane to alkenes in the presence of palladium(II) complexes begins with single-electron transfer from the palladium atom to polyhalomethane molecule, followed by fragmentation of the radical anion thus formed and generation of trichloromethyl radical. Halogen transfer to a carbon-centered radical arising from addition of trichloromethyl radical at the double bond occurs both from the polyhalomethane molecule and from halide palladium complex.

UR - http://www.scopus.com/inward/record.url?scp=3543063460&partnerID=8YFLogxK

U2 - 10.1023/B:RUJO.0000003181.02370.cf

DO - 10.1023/B:RUJO.0000003181.02370.cf

M3 - Article

AN - SCOPUS:3543063460

VL - 39

SP - 933

EP - 946

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 7

ER -

ID: 87469671