Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Addition of bromotrichloromethane and tetrachloromethane to cis-cyclooctene, cyclohexene, and norbornadiene in the presence of palladium(II) complexes. / Dneprovskii, A. S.; Ermoshkin, A. A.; Kasatochkin, A. N.; Boyarskii, V. P.
в: Russian Journal of Organic Chemistry, Том 39, № 7, 07.2003, стр. 933-946.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Addition of bromotrichloromethane and tetrachloromethane to cis-cyclooctene, cyclohexene, and norbornadiene in the presence of palladium(II) complexes
AU - Dneprovskii, A. S.
AU - Ermoshkin, A. A.
AU - Kasatochkin, A. N.
AU - Boyarskii, V. P.
N1 - Funding Information: This study was financially supported by the Russian Foundation for Basic Research (project no. 01-03-32 330a) and by the Universities of Russia Foundation (project no. UR.05.01.011).
PY - 2003/7
Y1 - 2003/7
N2 - Addition of bromotrichloromethane and tetrachloromethane to alkenes in the presence of palladium(II) complexes begins with single-electron transfer from the palladium atom to polyhalomethane molecule, followed by fragmentation of the radical anion thus formed and generation of trichloromethyl radical. Halogen transfer to a carbon-centered radical arising from addition of trichloromethyl radical at the double bond occurs both from the polyhalomethane molecule and from halide palladium complex.
AB - Addition of bromotrichloromethane and tetrachloromethane to alkenes in the presence of palladium(II) complexes begins with single-electron transfer from the palladium atom to polyhalomethane molecule, followed by fragmentation of the radical anion thus formed and generation of trichloromethyl radical. Halogen transfer to a carbon-centered radical arising from addition of trichloromethyl radical at the double bond occurs both from the polyhalomethane molecule and from halide palladium complex.
UR - http://www.scopus.com/inward/record.url?scp=3543063460&partnerID=8YFLogxK
U2 - 10.1023/B:RUJO.0000003181.02370.cf
DO - 10.1023/B:RUJO.0000003181.02370.cf
M3 - Article
AN - SCOPUS:3543063460
VL - 39
SP - 933
EP - 946
JO - Russian Journal of Organic Chemistry
JF - Russian Journal of Organic Chemistry
SN - 1070-4280
IS - 7
ER -
ID: 87469671