Результаты исследований: Научные публикации в периодических изданиях › статья
Actinyl Compounds with Hexavalent Elements (S, Cr, Se, Mo) – Structural Diversity, Nanoscale Chemistry, and Cellular Automata Modeling. / Krivovichev, S.V.
в: European Journal of Inorganic Chemistry, Том 2010, № 18, 2010, стр. 2594-2603.Результаты исследований: Научные публикации в периодических изданиях › статья
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TY - JOUR
T1 - Actinyl Compounds with Hexavalent Elements (S, Cr, Se, Mo) – Structural Diversity, Nanoscale Chemistry, and Cellular Automata Modeling
AU - Krivovichev, S.V.
PY - 2010
Y1 - 2010
N2 - Actinyl oxysalts with TO4 tetrahedral oxyanions (T = S, Se, Cr, Mo) demonstrate a remarkable structural diversity, owing to the flexibility of the An–O–T linkages, which results in a multitude of topological and geometrical variations. Application of graph representation of structural units allows topological classification of structures and analysis of topological and geometrical isomers. In some organically templated structures, isomerism is controlled by the interplay of hydrophobic/hydrophilic interactions between organic and inorganic substructures. The high flexibility of actinyl oxysalt complexes (in particular, in uranyl selenates) allows strong curvature of inorganic units and formation of curved nanoscale tubules assembled from [1+4+1] complexes. In some particular systems, the self-assembly process may be modeled using a cellular automata approach.
AB - Actinyl oxysalts with TO4 tetrahedral oxyanions (T = S, Se, Cr, Mo) demonstrate a remarkable structural diversity, owing to the flexibility of the An–O–T linkages, which results in a multitude of topological and geometrical variations. Application of graph representation of structural units allows topological classification of structures and analysis of topological and geometrical isomers. In some organically templated structures, isomerism is controlled by the interplay of hydrophobic/hydrophilic interactions between organic and inorganic substructures. The high flexibility of actinyl oxysalt complexes (in particular, in uranyl selenates) allows strong curvature of inorganic units and formation of curved nanoscale tubules assembled from [1+4+1] complexes. In some particular systems, the self-assembly process may be modeled using a cellular automata approach.
KW - Actinides
KW - Uranium
KW - Crystal structure
KW - Nanotubes
KW - Cellular automata
U2 - 10.1002/ejic.201000168
DO - 10.1002/ejic.201000168
M3 - статья
VL - 2010
SP - 2594
EP - 2603
JO - Berichte der deutschen chemischen Gesellschaft
JF - Berichte der deutschen chemischen Gesellschaft
SN - 0365-9496
IS - 18
ER -
ID: 5285125