Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
A thermally stable narrow-band green phosphor Na2MgAl10O17: Eu2+, Mn2+ for NUV LED application. / Zhang, Jiahui; Huang, Wenjing; Zeng, Linyun; Li, Chunli; Kolesnikov, Ilya E.; Umar, Zafari; Chen, Peican; Zhou, Liya; Liu, Wei; Zhang, Xinguo.
в: Ceramics International, Том 50, 15.11.2024, стр. 47604–47611.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - A thermally stable narrow-band green phosphor Na2MgAl10O17: Eu2+, Mn2+ for NUV LED application
AU - Zhang, Jiahui
AU - Huang, Wenjing
AU - Zeng, Linyun
AU - Li, Chunli
AU - Kolesnikov, Ilya E.
AU - Umar, Zafari
AU - Chen, Peican
AU - Zhou, Liya
AU - Liu, Wei
AU - Zhang, Xinguo
PY - 2024/11/15
Y1 - 2024/11/15
N2 - Thermally stable narrow-band green phosphor is important for phosphor-converted light emitting diodes (pc-LEDs). Herein, an efficient and stable Na2MgAl10O17: Eu2+, Mn2+ green phosphor is obtained using Eu2+-Mn2+ energy transfer strategy. The Mn2+ activator could be effectively sensitized by the addition of Eu2+ with significant UV absorption enhancement, then generates a bright green emission with peak at 515 nm and FWHM of 40 nm. The internal and external quantum efficiencies of optimal phosphor Na2MgAl10O17: 0.15Eu2+, 0.50Mn2+ are measured as 69.5 and 30.8 %, respectively. It is found that Na2MgAl10O17: Eu2+, Mn2+ phosphor shows good chemical and thermal stability, i.e. maintains no quenching after H2O/HCl soaking and keeps 90 % of RT intensity at 200 °C. By using Na2MgAl10O17: Eu2+, Mn2+ as converted phosphor, single-chromatic and white pc-LEDs were fabricated, which simultaneously achieve green and white emission with high brightness. Our results show that this Na2MgAl10O17: Eu2+, Mn2+ is a potential candidate as a thermally stable green phosphor for white LEDs.
AB - Thermally stable narrow-band green phosphor is important for phosphor-converted light emitting diodes (pc-LEDs). Herein, an efficient and stable Na2MgAl10O17: Eu2+, Mn2+ green phosphor is obtained using Eu2+-Mn2+ energy transfer strategy. The Mn2+ activator could be effectively sensitized by the addition of Eu2+ with significant UV absorption enhancement, then generates a bright green emission with peak at 515 nm and FWHM of 40 nm. The internal and external quantum efficiencies of optimal phosphor Na2MgAl10O17: 0.15Eu2+, 0.50Mn2+ are measured as 69.5 and 30.8 %, respectively. It is found that Na2MgAl10O17: Eu2+, Mn2+ phosphor shows good chemical and thermal stability, i.e. maintains no quenching after H2O/HCl soaking and keeps 90 % of RT intensity at 200 °C. By using Na2MgAl10O17: Eu2+, Mn2+ as converted phosphor, single-chromatic and white pc-LEDs were fabricated, which simultaneously achieve green and white emission with high brightness. Our results show that this Na2MgAl10O17: Eu2+, Mn2+ is a potential candidate as a thermally stable green phosphor for white LEDs.
KW - Green phosphor
KW - Mn2+ sensitization
KW - Thermally stable emission
KW - White LEDs
UR - https://www.mendeley.com/catalogue/3d8109a6-306e-371f-a980-64fcc6f25e0e/
U2 - 10.1016/j.ceramint.2024.09.106
DO - 10.1016/j.ceramint.2024.09.106
M3 - Article
VL - 50
SP - 47604
EP - 47611
JO - Ceramics International
JF - Ceramics International
SN - 0272-8842
ER -
ID: 126136442