TY - JOUR

T1 - A Solution-Solid Phase Equilibrium in Ternary Systems Containing d-Elements Salts and Mixed Oxygen-Donor Solvent

AU - Bogachev, N.A.

AU - Gorbunov, A.O.

AU - Skripkin, M. Yu

AU - Nikol’skii, A.B.

PY - 2019/6/1

Y1 - 2019/6/1

N2 - The results of the study of ternary systems containing copper, cobalt, nickel, and cadmium halides and sulfates in binary water-organic and mixed organic solvents are summarized. The influence of the donor-acceptor properties of the ternary system components, the relative dielectric permittivity, and the intermolecular association in the mixed solvent on the solubility of salts and the crystalline structure of solvates is analyzed.

AB - The results of the study of ternary systems containing copper, cobalt, nickel, and cadmium halides and sulfates in binary water-organic and mixed organic solvents are summarized. The influence of the donor-acceptor properties of the ternary system components, the relative dielectric permittivity, and the intermolecular association in the mixed solvent on the solubility of salts and the crystalline structure of solvates is analyzed.

KW - competing solvation

KW - crystal solvates

KW - d-elements salts

KW - electrolyte solutions

KW - solubility

KW - ternary systems

KW - KIRKWOOD-BUFF

KW - CRYSTAL-STRUCTURES

KW - IONS

KW - AQUEOUS-ORGANIC SOLVENTS

KW - SOLUBILITY

KW - PREFERENTIAL SOLVATION

KW - BROMIDE

KW - DIMETHYL-SULFOXIDE

KW - COPPER(II) CHLORIDE

KW - CADMIUM IODIDE COMPLEXES

UR - http://www.scopus.com/inward/record.url?scp=85068704472&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/solutionsolid-phase-equilibrium-ternary-systems-containing-delements-salts-mixed-oxygendonor-solvent

U2 - 10.1134/S1070363219060082

DO - 10.1134/S1070363219060082

M3 - Article

AN - SCOPUS:85068704472

VL - 89

SP - 1142

EP - 1153

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 6

ER -