TY - JOUR

T1 - A review on ion transport pathways and coordination chemistry between ions and electrolytes in energy storage devices

AU - Gerdroodbar, Amirhossein Enayati

AU - Alihemmati , Hura

AU - Safavi-Mirmahaleh , Seyedeh-Arefeh

AU - Golshan , Marzieh

AU - Damircheli , Roya

AU - Елисеева, Светлана Николаевна

AU - Salami-Kalajahi , Mehdi

PY - 2023/12/25

Y1 - 2023/12/25

N2 - The design and construction of energy storage systems, such as batteries and supercapacitors, represent one ofthe most pioneering research domains in scientific landscape. Consequently, electrolytes assume a pivotal role asindispensable components, while a profound understanding of electrolyte chemistry and ion transfer pathwaysthrough electrolyte emerges as a potent tool for optimizing storage device design. This field of knowledge, knownas coordination chemistry, elucidates the intricate interplay between ions, solvents, salts, and the electrolytematrix, comprising polymer chains and ceramics, thereby providing invaluable insights into potential iontransport pathways. Thus, this discourse commences with an introduction and classification of electrolytes,followed by an in-depth exploration of ion transfer pathways in each case. Furthermore, the impact of the matrix,solvent, and salt on complex formation, ion coordination chemistry, and ionic conductivity is meticulouslyexamined, thereby enhancing comprehension of these fundamental aspects.

AB - The design and construction of energy storage systems, such as batteries and supercapacitors, represent one ofthe most pioneering research domains in scientific landscape. Consequently, electrolytes assume a pivotal role asindispensable components, while a profound understanding of electrolyte chemistry and ion transfer pathwaysthrough electrolyte emerges as a potent tool for optimizing storage device design. This field of knowledge, knownas coordination chemistry, elucidates the intricate interplay between ions, solvents, salts, and the electrolytematrix, comprising polymer chains and ceramics, thereby providing invaluable insights into potential iontransport pathways. Thus, this discourse commences with an introduction and classification of electrolytes,followed by an in-depth exploration of ion transfer pathways in each case. Furthermore, the impact of the matrix,solvent, and salt on complex formation, ion coordination chemistry, and ionic conductivity is meticulouslyexamined, thereby enhancing comprehension of these fundamental aspects.

KW - Energy storage system

KW - Electrolytes

KW - Ionic conductivity

KW - coordination chemistry

U2 - 10.1016/j.est.2023.109311

DO - 10.1016/j.est.2023.109311

M3 - Article

VL - 74

JO - Journal of Energy Storage

JF - Journal of Energy Storage

SN - 2352-152X

IS - Part A

M1 - 109311

ER -