Standard

A Novel Multi-Ionophore Approach for Potentiometric Analysis of Lanthanide Mixtures. / Ashina, Julia ; Babain, Vasily ; Kirsanov, Dmitry ; Legin, Andrey .

в: Chemosensors, Том 9, № 2, 23, 02.2021.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Ashina, J, Babain, V, Kirsanov, D & Legin, A 2021, 'A Novel Multi-Ionophore Approach for Potentiometric Analysis of Lanthanide Mixtures', Chemosensors, Том. 9, № 2, 23. https://doi.org/10.3390/chemosensors9020023

APA

Ashina, J., Babain, V., Kirsanov, D., & Legin, A. (2021). A Novel Multi-Ionophore Approach for Potentiometric Analysis of Lanthanide Mixtures. Chemosensors, 9(2), [23]. https://doi.org/10.3390/chemosensors9020023

Vancouver

Ashina J, Babain V, Kirsanov D, Legin A. A Novel Multi-Ionophore Approach for Potentiometric Analysis of Lanthanide Mixtures. Chemosensors. 2021 Февр.;9(2). 23. https://doi.org/10.3390/chemosensors9020023

Author

Ashina, Julia ; Babain, Vasily ; Kirsanov, Dmitry ; Legin, Andrey . / A Novel Multi-Ionophore Approach for Potentiometric Analysis of Lanthanide Mixtures. в: Chemosensors. 2021 ; Том 9, № 2.

BibTeX

@article{4918b98692794abbab436e13d823dc93,
title = "A Novel Multi-Ionophore Approach for Potentiometric Analysis of Lanthanide Mixtures",
abstract = "This work aims to discuss quantification of rare earth metals in a complex mixture using the novel multi-ionophore approach based on potentiometric sensor arrays. Three compounds previously tested as extracting agents in reprocessing of spent nuclear fuel were applied as ionophores in polyvinyl chloride (PVC)-plasticized membranes of potentiometric sensors. Seven types of sensors containing these ionophores were prepared and assembled into a sensor array. The multi-ionophore array performance was evaluated in the analysis of Ln3+ mixtures and compared to that of conventional monoionophore sensors. It was demonstrated that a multi-ionophore array can yield RMSEP (root mean-squared error of prediction) values not exceeding 0.15 logC for quantification of individual lanthanides in binary mixtures in a concentration range 5 to 3 pLn3+.",
keywords = "potentiometric sensors, lanthanides, multisensory systems, sensor arrays, Potentiometric sensors, Lanthanides, Multisensory systems, Sensor arrays",
author = "Julia Ashina and Vasily Babain and Dmitry Kirsanov and Andrey Legin",
note = "Publisher Copyright: {\textcopyright} 2021 by the authors. Licensee MDPI, Basel, Switzerland.",
year = "2021",
month = feb,
doi = "10.3390/chemosensors9020023",
language = "English",
volume = "9",
journal = "Chemosensors",
issn = "2227-9040",
publisher = "MDPI AG",
number = "2",

}

RIS

TY - JOUR

T1 - A Novel Multi-Ionophore Approach for Potentiometric Analysis of Lanthanide Mixtures

AU - Ashina, Julia

AU - Babain, Vasily

AU - Kirsanov, Dmitry

AU - Legin, Andrey

N1 - Publisher Copyright: © 2021 by the authors. Licensee MDPI, Basel, Switzerland.

PY - 2021/2

Y1 - 2021/2

N2 - This work aims to discuss quantification of rare earth metals in a complex mixture using the novel multi-ionophore approach based on potentiometric sensor arrays. Three compounds previously tested as extracting agents in reprocessing of spent nuclear fuel were applied as ionophores in polyvinyl chloride (PVC)-plasticized membranes of potentiometric sensors. Seven types of sensors containing these ionophores were prepared and assembled into a sensor array. The multi-ionophore array performance was evaluated in the analysis of Ln3+ mixtures and compared to that of conventional monoionophore sensors. It was demonstrated that a multi-ionophore array can yield RMSEP (root mean-squared error of prediction) values not exceeding 0.15 logC for quantification of individual lanthanides in binary mixtures in a concentration range 5 to 3 pLn3+.

AB - This work aims to discuss quantification of rare earth metals in a complex mixture using the novel multi-ionophore approach based on potentiometric sensor arrays. Three compounds previously tested as extracting agents in reprocessing of spent nuclear fuel were applied as ionophores in polyvinyl chloride (PVC)-plasticized membranes of potentiometric sensors. Seven types of sensors containing these ionophores were prepared and assembled into a sensor array. The multi-ionophore array performance was evaluated in the analysis of Ln3+ mixtures and compared to that of conventional monoionophore sensors. It was demonstrated that a multi-ionophore array can yield RMSEP (root mean-squared error of prediction) values not exceeding 0.15 logC for quantification of individual lanthanides in binary mixtures in a concentration range 5 to 3 pLn3+.

KW - potentiometric sensors

KW - lanthanides

KW - multisensory systems

KW - sensor arrays

KW - Potentiometric sensors

KW - Lanthanides

KW - Multisensory systems

KW - Sensor arrays

UR - https://www.mendeley.com/catalogue/78d8fe70-11f2-376f-bf13-f9fc34c24d2b/

UR - http://www.scopus.com/inward/record.url?scp=85100594384&partnerID=8YFLogxK

U2 - 10.3390/chemosensors9020023

DO - 10.3390/chemosensors9020023

M3 - Article

VL - 9

JO - Chemosensors

JF - Chemosensors

SN - 2227-9040

IS - 2

M1 - 23

ER -

ID: 73554440