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A nonpolar bond to hydrogen vs. lone pair: incorporation of HPO32- and SeO32- into a lead perrhenate framework. / Чаркин, Д. О.; Гришаев, Василий Юрьевич; Борисов, Артем Сергеевич; Чачин, Павел; Назарчук, Евгений Васильевич; Сийдра, Олег Иоханнесович.

в: Journal of Solid State Chemistry, Том 318, 123706, 01.02.2023.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{589f512fc7bd4fa4838bd832bf0dde13,
title = "A nonpolar bond to hydrogen vs. lone pair: incorporation of HPO32- and SeO32- into a lead perrhenate framework",
abstract = "Two new lead perrhenate compounds, [Pb2(ReO4)2(SeO3)H2O]H2O (1) and [Pb2(ReO4)2(HPO3)H2O]H2O (2), were prepared by adding selenious or phosphorous acid to boiling concentrated solutions of lead perrhenate. Both compounds adopt the same crystal structure illustrating similar structural impact of lone pair and nonpolar hydrogen bond on one-sided coordination and formation of loose structural architectures. The crystal structure of 1 and 2, which corresponds to a novel structure type, consists of lead-perrhenate double layers interconnected by the selenite or phosphite anions into framework; the channels are filled by water molecules. We briefly discuss the chemistry of compounds containing both regular-shaped and {\textquoteleft}lone-pair{\textquoteright} or {\textquoteleft}inert bond{\textquoteright} anions.",
keywords = "Lead, Lone pair, Perrhenate, Phosphite, Selenite",
author = "Чаркин, {Д. О.} and Гришаев, {Василий Юрьевич} and Борисов, {Артем Сергеевич} and Павел Чачин and Назарчук, {Евгений Васильевич} and Сийдра, {Олег Иоханнесович}",
year = "2023",
month = feb,
day = "1",
doi = "10.1016/j.jssc.2022.123706",
language = "English",
volume = "318",
journal = "Journal of Solid State Chemistry",
issn = "0022-4596",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - A nonpolar bond to hydrogen vs. lone pair: incorporation of HPO32- and SeO32- into a lead perrhenate framework

AU - Чаркин, Д. О.

AU - Гришаев, Василий Юрьевич

AU - Борисов, Артем Сергеевич

AU - Чачин, Павел

AU - Назарчук, Евгений Васильевич

AU - Сийдра, Олег Иоханнесович

PY - 2023/2/1

Y1 - 2023/2/1

N2 - Two new lead perrhenate compounds, [Pb2(ReO4)2(SeO3)H2O]H2O (1) and [Pb2(ReO4)2(HPO3)H2O]H2O (2), were prepared by adding selenious or phosphorous acid to boiling concentrated solutions of lead perrhenate. Both compounds adopt the same crystal structure illustrating similar structural impact of lone pair and nonpolar hydrogen bond on one-sided coordination and formation of loose structural architectures. The crystal structure of 1 and 2, which corresponds to a novel structure type, consists of lead-perrhenate double layers interconnected by the selenite or phosphite anions into framework; the channels are filled by water molecules. We briefly discuss the chemistry of compounds containing both regular-shaped and ‘lone-pair’ or ‘inert bond’ anions.

AB - Two new lead perrhenate compounds, [Pb2(ReO4)2(SeO3)H2O]H2O (1) and [Pb2(ReO4)2(HPO3)H2O]H2O (2), were prepared by adding selenious or phosphorous acid to boiling concentrated solutions of lead perrhenate. Both compounds adopt the same crystal structure illustrating similar structural impact of lone pair and nonpolar hydrogen bond on one-sided coordination and formation of loose structural architectures. The crystal structure of 1 and 2, which corresponds to a novel structure type, consists of lead-perrhenate double layers interconnected by the selenite or phosphite anions into framework; the channels are filled by water molecules. We briefly discuss the chemistry of compounds containing both regular-shaped and ‘lone-pair’ or ‘inert bond’ anions.

KW - Lead

KW - Lone pair

KW - Perrhenate

KW - Phosphite

KW - Selenite

UR - https://www.mendeley.com/catalogue/4cd661c0-0a5f-38ca-a826-ecc4d70e7d17/

U2 - 10.1016/j.jssc.2022.123706

DO - 10.1016/j.jssc.2022.123706

M3 - Article

VL - 318

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

M1 - 123706

ER -

ID: 100038283