Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
A nonpolar bond to hydrogen vs. lone pair: incorporation of HPO32- and SeO32- into a lead perrhenate framework. / Чаркин, Д. О.; Гришаев, Василий Юрьевич; Борисов, Артем Сергеевич; Чачин, Павел; Назарчук, Евгений Васильевич; Сийдра, Олег Иоханнесович.
в: Journal of Solid State Chemistry, Том 318, 123706, 01.02.2023.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - A nonpolar bond to hydrogen vs. lone pair: incorporation of HPO32- and SeO32- into a lead perrhenate framework
AU - Чаркин, Д. О.
AU - Гришаев, Василий Юрьевич
AU - Борисов, Артем Сергеевич
AU - Чачин, Павел
AU - Назарчук, Евгений Васильевич
AU - Сийдра, Олег Иоханнесович
PY - 2023/2/1
Y1 - 2023/2/1
N2 - Two new lead perrhenate compounds, [Pb2(ReO4)2(SeO3)H2O]H2O (1) and [Pb2(ReO4)2(HPO3)H2O]H2O (2), were prepared by adding selenious or phosphorous acid to boiling concentrated solutions of lead perrhenate. Both compounds adopt the same crystal structure illustrating similar structural impact of lone pair and nonpolar hydrogen bond on one-sided coordination and formation of loose structural architectures. The crystal structure of 1 and 2, which corresponds to a novel structure type, consists of lead-perrhenate double layers interconnected by the selenite or phosphite anions into framework; the channels are filled by water molecules. We briefly discuss the chemistry of compounds containing both regular-shaped and ‘lone-pair’ or ‘inert bond’ anions.
AB - Two new lead perrhenate compounds, [Pb2(ReO4)2(SeO3)H2O]H2O (1) and [Pb2(ReO4)2(HPO3)H2O]H2O (2), were prepared by adding selenious or phosphorous acid to boiling concentrated solutions of lead perrhenate. Both compounds adopt the same crystal structure illustrating similar structural impact of lone pair and nonpolar hydrogen bond on one-sided coordination and formation of loose structural architectures. The crystal structure of 1 and 2, which corresponds to a novel structure type, consists of lead-perrhenate double layers interconnected by the selenite or phosphite anions into framework; the channels are filled by water molecules. We briefly discuss the chemistry of compounds containing both regular-shaped and ‘lone-pair’ or ‘inert bond’ anions.
KW - Lead
KW - Lone pair
KW - Perrhenate
KW - Phosphite
KW - Selenite
UR - https://www.mendeley.com/catalogue/4cd661c0-0a5f-38ca-a826-ecc4d70e7d17/
U2 - 10.1016/j.jssc.2022.123706
DO - 10.1016/j.jssc.2022.123706
M3 - Article
VL - 318
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
M1 - 123706
ER -
ID: 100038283