TY - JOUR

T1 - 9-Vinyl-9H-carbazole-3,6-dicarbonitrile

AU - Svetlova, Kristina

AU - Kazantsev, Alexander

AU - Levin, Oleg

AU - Filippova, Sofia

AU - Alekseeva, Elena

PY - 2024/2/2

Y1 - 2024/2/2

N2 - Carbazole polymers attract significant attention as promising luminophores, organic electronic and photovoltaic materials, photo/electrocatalysts, energy storage materials, redox mediators and catalysts. However, the oxidation potential of the commercially available poly(vinylcarbazole) is insufficient for some applications such as high-voltage Li-Ion batteries. We have proposed a monomer for the novel polycarbazole with an increased oxidation potential, which will be compatible with high-voltage cathode materials for Li-Ion. In addition, the proposed polymer is an interesting substrate for the further carbonization to obtain N-doped carbons with a high electrocatalytic activity level.

AB - Carbazole polymers attract significant attention as promising luminophores, organic electronic and photovoltaic materials, photo/electrocatalysts, energy storage materials, redox mediators and catalysts. However, the oxidation potential of the commercially available poly(vinylcarbazole) is insufficient for some applications such as high-voltage Li-Ion batteries. We have proposed a monomer for the novel polycarbazole with an increased oxidation potential, which will be compatible with high-voltage cathode materials for Li-Ion. In addition, the proposed polymer is an interesting substrate for the further carbonization to obtain N-doped carbons with a high electrocatalytic activity level.

KW - carbazole

KW - cyanation

KW - one pot

KW - vinylation

UR - https://www.mendeley.com/catalogue/a35184bd-db4a-39cf-80d7-64a5f2bdb5f0/

U2 - 10.3390/M1768

DO - 10.3390/M1768

M3 - Letter

VL - 2024

JO - MolBank

JF - MolBank

SN - 1422-8599

IS - 1

M1 - M1768

ER -