Результаты исследований: Научные публикации в периодических изданиях › статья
5-Phenyl-2H-tetrazol-2-ylmethyl Ketones in the Synthesis of Tetrazolylalkanols and Tetrazolyl(hydroxy)alkylphosphonates. / Krylov, A.S.; Dogadina, A.V.; Trifonov, R.E.
в: Russian Journal of Organic Chemistry, Том 50, № 6, 2014, стр. 892-894.Результаты исследований: Научные публикации в периодических изданиях › статья
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TY - JOUR
T1 - 5-Phenyl-2H-tetrazol-2-ylmethyl Ketones in the Synthesis of Tetrazolylalkanols and Tetrazolyl(hydroxy)alkylphosphonates
AU - Krylov, A.S.
AU - Dogadina, A.V.
AU - Trifonov, R.E.
PY - 2014
Y1 - 2014
N2 - The reduction of 1-(5-phenyl-2H-tetrazol-2-yl)propan-2-one and 1-phenyl-2-(5-phenyl-2H-tetrazol- 2-yl)ethanone with sodium tetrahydridoborate gave 1-(5-phenyl-2H-tetrazol-2-yl)propan-1-ol and 1-phenyl-2- (5-phenyl-2H-tetrazol-2-yl)ethanol, respectively. Only 1-(5-phenyl-2H-tetrazol-2-yl)propan-2-one was reduced with baker’s yeast with an appreciable yield. 1-(5-Phenyl-2H-tetrazol-2-yl)propan-2-one and 1-phenyl-2-(5- phenyl-2H-tetrazol-2-yl)ethanone reacted with diethyl phosphonate in the presence of potassium fluoride to produce the corresponding diethyl [hydroxy(5-phenyl-2H-tetrazol-2-yl)alkyl]phosphonates.
AB - The reduction of 1-(5-phenyl-2H-tetrazol-2-yl)propan-2-one and 1-phenyl-2-(5-phenyl-2H-tetrazol- 2-yl)ethanone with sodium tetrahydridoborate gave 1-(5-phenyl-2H-tetrazol-2-yl)propan-1-ol and 1-phenyl-2- (5-phenyl-2H-tetrazol-2-yl)ethanol, respectively. Only 1-(5-phenyl-2H-tetrazol-2-yl)propan-2-one was reduced with baker’s yeast with an appreciable yield. 1-(5-Phenyl-2H-tetrazol-2-yl)propan-2-one and 1-phenyl-2-(5- phenyl-2H-tetrazol-2-yl)ethanone reacted with diethyl phosphonate in the presence of potassium fluoride to produce the corresponding diethyl [hydroxy(5-phenyl-2H-tetrazol-2-yl)alkyl]phosphonates.
U2 - 10.1134/S1070428014060219
DO - 10.1134/S1070428014060219
M3 - Article
VL - 50
SP - 892
EP - 894
JO - Russian Journal of Organic Chemistry
JF - Russian Journal of Organic Chemistry
SN - 1070-4280
IS - 6
ER -
ID: 7013232