TY - JOUR

T1 - 4,5-diiodo-1-H-imidazole-derived linker ligand and Cu(I) and Co(II) coordination polymers based thereupon

AU - Zaguzin, Alexander S

AU - Zaitsev, Artem V

AU - Korobeynikov, Nikita A.

AU - Novikov, Alexander S.

AU - Usoltsev, Andrey N.

AU - Fedin, Vladimir P

AU - Adonin, Sergey A

PY - 2024

Y1 - 2024

N2 - The new iodine-rich imidazole derivative 1,4-bis(4,5-diiodo-1H-imidazol-1-yl)butane (bimbI4, 1) features multiple I···I interactions in solid state. Using 1 as precursor, we prepared 1D and 2D coordination polymers of Co(II) and Cu(I)...The new iodine-rich imidazole derivative 1,4-bis(4,5-diiodo-1H-imidazol-1-yl)butane (bimbI4, 1) features multiple I···I interactions in solid state. Using 1 as precursor, we prepared 1D and 2D coordination polymers of Co(II) and Cu(I) – {[Co(bimbI4)Cl2]·1.5DMF}n (2) and {[Cu2I2(bimbI4)]}n (3), respectively, also featuring extended systems of halogen bonds within their structures.

AB - The new iodine-rich imidazole derivative 1,4-bis(4,5-diiodo-1H-imidazol-1-yl)butane (bimbI4, 1) features multiple I···I interactions in solid state. Using 1 as precursor, we prepared 1D and 2D coordination polymers of Co(II) and Cu(I)...The new iodine-rich imidazole derivative 1,4-bis(4,5-diiodo-1H-imidazol-1-yl)butane (bimbI4, 1) features multiple I···I interactions in solid state. Using 1 as precursor, we prepared 1D and 2D coordination polymers of Co(II) and Cu(I) – {[Co(bimbI4)Cl2]·1.5DMF}n (2) and {[Cu2I2(bimbI4)]}n (3), respectively, also featuring extended systems of halogen bonds within their structures.

UR - https://www.mendeley.com/catalogue/83e2f143-2503-3e7b-93f3-6cefe0377c87/

U2 - 10.1039/d4ce00072b

DO - 10.1039/d4ce00072b

M3 - Article

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

ER -