Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
2-hydroxy-3-(4-oxy(2,2,6,6-tetramethylpiperidin-1-oxyl)butoxy)benzaldehyde. / Vereshchagin, Anatoliy A.; Novoselova, Julia V.; Kalnin, Arseniy Y.; Lukyanov, Daniil A.
в: MolBank, Том 2021, № 3, M1245, 09.2021.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - 2-hydroxy-3-(4-oxy(2,2,6,6-tetramethylpiperidin-1-oxyl)butoxy)benzaldehyde
AU - Vereshchagin, Anatoliy A.
AU - Novoselova, Julia V.
AU - Kalnin, Arseniy Y.
AU - Lukyanov, Daniil A.
N1 - Publisher Copyright: © 2021 by the authors. Licensee MDPI, Basel, Switzerland.
PY - 2021/9
Y1 - 2021/9
N2 - Salen-type complexes with transition metals and corresponding polymers attract great scientific interest due to their high electrochemical properties and potential for use as part of next generation organic energy storage devices. Because of their good conductivity but relatively low capacity, energy-intensive additives such as quinones or TEMPO fragments can significantly en-hance the capacitive characteristics of the electrode materials. Herein, we report a preparation of precursor for a modified Salen-type complex, the substituted 2,3-Dihydroxybenzaldehyde by butoxy linkers with TEMPO fragment using alkylation reaction. The resulting product was characterized by the1H and13C, COSY, HMBC, HSQC nuclear magnetic resonance (NMR), ESI–high resolution mass spectrometry (ESI–HRMS), and Fourier-transform infrared spectroscopy (FTIR). The reported approach opens the way for easy modification of Salen-type complexes in order to increase their specific characteristics.
AB - Salen-type complexes with transition metals and corresponding polymers attract great scientific interest due to their high electrochemical properties and potential for use as part of next generation organic energy storage devices. Because of their good conductivity but relatively low capacity, energy-intensive additives such as quinones or TEMPO fragments can significantly en-hance the capacitive characteristics of the electrode materials. Herein, we report a preparation of precursor for a modified Salen-type complex, the substituted 2,3-Dihydroxybenzaldehyde by butoxy linkers with TEMPO fragment using alkylation reaction. The resulting product was characterized by the1H and13C, COSY, HMBC, HSQC nuclear magnetic resonance (NMR), ESI–high resolution mass spectrometry (ESI–HRMS), and Fourier-transform infrared spectroscopy (FTIR). The reported approach opens the way for easy modification of Salen-type complexes in order to increase their specific characteristics.
KW - Alkylation
KW - Linkers
KW - Salen precursor
KW - TEMPO
UR - http://www.scopus.com/inward/record.url?scp=85111012356&partnerID=8YFLogxK
U2 - 10.3390/M1245
DO - 10.3390/M1245
M3 - Article
AN - SCOPUS:85111012356
VL - 2021
JO - MolBank
JF - MolBank
SN - 1422-8599
IS - 3
M1 - M1245
ER -
ID: 100348048